journal article·2013-11-01Open access

Tin-phosphate glass anode for sodium ion batteries

Tsuyoshi Honma, Takuya Togashi, Hiroatsu Kondo, Takayuki Komatsu, Hideo Yamauchi, Akihiko Sakamoto, Tetsuo Sakai

APL Materials· Volume 1· Issue 5

Abstract

The electrochemical property of tin-phosphate (designate as GSPO) glass anode for the sodium ion battery was studied. During the first charge process, sodium ion diffused into GSPO glass matrix and due to the reduction of Sn2+ to Sn0 state sodiated tin metal nano-size particles are formed in oxide glass matrix. After the second cycle, we confirmed the steady reversible reaction ∼320 mAh/g at 0–1 V cutoff voltage condition by alloying process in NaxSn4. The tin-phosphate glass is a promising candidate of new anode active material that realizes high energy density sodium ion batteries.
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Research context

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Semiconductor materials and interfaces

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Nagaoka University of Technology 1 Department of Materials Science and Technology, , Kamitomioka 1603-1, Nagaoka, Niigata 940-2188, Japan

Nippon Electric Glass Co., Ltd. 2 , 2-7-1 Seiran Otsu, Shiga 520-8639, Japan

National Institute of Advanced Industrial Science and Technology 3 , 1-8-31 Midorigaoka Ikeda, Osaka 563-8577, Japan

References (22)

Show source-provided references
1. Energy Environ. Sci. · 2013 · 6 · 231210.1039/C3EE41031E ↗
2. Electrochem. Commun. · 2010 · 12 · 35510.1016/j.elecom.2009.12.033 ↗
3. ECS Meet. Abstr. · 2006 · 602 · 201
4. Nature Mater. · 2012 · 11 · 51210.1038/nmat3309 ↗
5. J. Ceram. Soc. Jpn. · 2012 · 120 · 34410.2109/jcersj2.120.344 ↗
6. J. Power Sources · 2013 · 227 · 3110.1016/j.jpowsour.2012.11.030 ↗
7. Adv. Funct. Mater. · 2011 · 21 · 385910.1002/adfm.201100854 ↗
8. J. Electrochem. Soc. · 2011 · 158 · A101110.1149/1.3607983 ↗
9. Chem. Mater. · 2011 · 23 · 410910.1021/cm202076g ↗
10. Chem. Commun. · 2013 · 49 · 313110.1039/c3cc40448j ↗
11. J. Electrochem. Soc. · 2013 · 160 · A172510.1149/2.049310jes ↗
12. Science · 1997 · 276 · 139510.1126/science.276.5317.1395 ↗
13. J. Electrochem. Soc. · 1997 · 144 · 204510.1149/1.1837740 ↗
14. J. Electrochem. Soc. · 1997 · 144 · 294310.1149/1.1837941 ↗
15. J. Mater. Chem. · 2000 · 10 · 124110.1039/b001352h ↗
16. J. Ceram. Soc. Jpn. · 2001 · 109 · 101010.2109/jcersj.109.1276_1010 ↗
17. J. Ceram. Soc. Jpn. · 2004 · 112 · S713
18. J. Non-Cryst. Solids · 2004 · 345–346 · 47810.1016/j.jnoncrysol.2004.08.069 ↗
19. J. Electrochem. Soc. · 2003 · 150 · A58210.1149/1.1565134 ↗
20. J. Non-Cryst. Solids · 2008 · 354 · 38010.1016/j.jnoncrysol.2007.07.047 ↗
21. Nano Lett. · 2012 · 12 · 589710.1021/nl303305c ↗
22. J. Electrochem. Soc. · 2012 · 159 · AI80110.1149/2.037211jes ↗