journal article·2014-12-01Open access

A new MOF-5 homologue for selective separation of methane from C2 hydrocarbons at room temperature

Yabing He, Chengling Song, Yajing Ling, Chuande Wu, Rajamani Krishna, Banglin Chen

APL Materials· Volume 2· Issue 12

Abstract

A new MOF-5 homologue compound UTSA-10 has been obtained under solvothermal conditions from a mixture of Zn(NO3)2⋅6H2O and commercially available linker, 2-methylfumaric acid, in N,N-dimethylformamide. The moderate surface area and suitable pore sizes enable the activated UTSA-10a to separate methane from C2 hydrocarbons at room temperature.
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Research context

OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Inorganic Fluorides and Related Compounds · Covalent Organic Framework Applications

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Affiliations

Zhejiang Normal University 1 College of Chemistry and Life Sciences, , Jinhua 321004, China

Zhejiang University 2 Department of Chemistry, , Hangzhou 310027, China

University of Amsterdam 3 Van’t Hoff Institute for Molecular Sciences, , Science Park 904, 1098 XH Amsterdam, The Netherlands

University of Texas at San Antonio 4 Department of Chemistry, , One UTSA Circle, San Antonio, Texas 78249-0698, USA

King Abdulaziz University 5 Department of Chemistry, Faculty of Science, , Jeddah 22254, Saudi Arabia

Funding

Welch Foundation · National Natural Science Foundation of China

References (33)

Show source-provided references
1. Chem. Rev. · 2012 · 112 · 112610.1021/cr200101d ↗
2. Chem. Soc. Rev. · 2014 · 43 · 565710.1039/C4CS00032C ↗
3. Chem. Rev. · 2012 · 112 · 123210.1021/cr200256v ↗
4. Chem. Rev. · 2012 · 112 · 86910.1021/cr200190s ↗
5. Chem. Rev. · 2012 · 112 · 110510.1021/cr200324t ↗
6. Chem. Rev. · 2012 · 112 · 83610.1021/cr200216x ↗
7. Angew. Chem., Int. Ed. · 2004 · 43 · 233410.1002/anie.200300610 ↗
8. Chem. Rev. · 2012 · 112 · 78210.1021/cr200274s ↗
9. Chem. Commun. · 2011 · 47 · 335110.1039/c0cc05419d ↗
10. Chem. Soc. Rev. · 2009 · 38 · 124810.1039/b807083k ↗
11. Adv. Mater. · 2010 · 22 · 411210.1002/adma.201000197 ↗
12. Chem. - Eur. J. · 2011 · 17 · 781710.1002/chem.201100350 ↗
13. Energy Environ. Sci. · 2012 · 5 · 910710.1039/c2ee22858k ↗
14. Chem. Sci. · 2012 · 3 · 11610.1039/c1sc00591j ↗
15. Science · 2012 · 335 · 160610.1126/science.1217544 ↗
16. Cryst. Growth Des. · 2013 · 13 · 209410.1021/cg400164m ↗
17. Chem. - Eur. J. · 2014 · 20 · 907310.1002/chem.201304962 ↗
18. Nature · 1999 · 402 · 27610.1038/46248 ↗
19. Science · 2002 · 295 · 46910.1126/science.1067208 ↗
20. Inorg. Chem. · 2009 · 48 · 464910.1021/ic900486r ↗
21. See supplementary material at http://dx.doi.org/10.1063/1.4897351 for thermal gravimetric analysis; powder X-ray diffraction patterns before and after activation; the BET and Langmuir analysis of N2 adsorption isotherms; and the Langmuir-Freundlich fits of the gas adsorption isotherms.
22. Chem. Commun. · 2012 · 48 · 1181310.1039/c2cc35418g ↗
23. Chem. Commun. · 2012 · 48 · 1085610.1039/c2cc35729a ↗
24. Chem. Commun. · 2012 · 48 · 649310.1039/c2cc31792c ↗
25. Chem. - Eur. J. · 2012 · 18 · 61310.1002/chem.201102734 ↗
26. Chem. - Eur. J. · 2012 · 18 · 190110.1002/chem.201103927 ↗
27. Nature Commun. · 2012 · 2 · 20410.1038/ncomms1206 ↗
28. J. Mater. Chem. A · 2013 · 1 · 7710.1039/c2ta00155a ↗
29. J. Am. Chem. Soc. · 2012 · 134 · 870310.1021/ja302380x ↗
30. J. Am. Chem. Soc. · 2009 · 131 · 1241510.1021/ja904782h ↗
31. AIChE J. · 1965 · 11 · 12110.1002/aic.690110125 ↗
32. J. Phys. Chem. C · 2011 · 115 · 1294110.1021/jp202203c ↗
33. J. Phys. Chem. C · 2012 · 116 · 1660910.1021/jp3046356 ↗