DataVXAPL MaterialsPaper
journal article·2014-11Open access

In situ transmission electron microscopy investigation of the interfacial reaction between Ni and Al during rapid heating in a nanocalorimeter

Michael D. Grapes, Thomas LaGrange, Karsten Woll, Bryan W. Reed, Geoffrey H. Campbell, David A. LaVan, Timothy P. Weihs

APL Materials· Volume 2· Issue 11
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Source abstract

Abstract

The Al/Ni formation reaction is highly exothermic and of both scientific and technological significance. In this report, we study the evolution of intermetallic phases in this reaction at a heating rate of 830 K/s. 100-nm-thick Al/Ni bilayers were deposited onto nanocalorimeter sensors that enable the measurement of temperature and heat flow during rapid heating. Time-resolved transmission electron diffraction patterns captured simultaneously with thermal measurements allow us to identify the intermetallic phases present and reconstruct the phase transformation sequence as a function of time and temperature. The results show a mostly unaltered phase transformation sequence compared to lower heating rates.
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Research context

Metals & alloysNanomaterials

OpenAlex topics: nanoparticles nucleation surface interactions · Semiconductor materials and interfaces · Advanced Chemical Physics Studies

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Affiliations

Department of Materials Science and Engineering, Johns Hopkins University, Baltimore, Maryland 21218, USA

Material Measurement Laboratory, Materials Measurement Science Division, National Institute of Standards and Technology, Gaithersburg, Maryland 20899, USA

Lawrence Livermore National Laboratory, Materials Science and Technology Division, Livermore, California 94550, USA

Institute of Applied Materials, Karlsruhe Institute of Technology, 76344 Eggenstein-Leopoldshafen, Germany

Funding

National Science Foundation (NSF) · U.S. Department of Energy (DOE) · National Institute of Standards and Technology (NIST) · Basic Energy Sciences (BES)

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