journal article·2024-10-01Open access

Epitaxial RuO2 and IrO2 films by pulsed laser deposition on TiO2(110)

P. Keßler, T. Waldsauer, V. Jovic, M. Kamp, M. Schmitt, M. Sing, R. Claessen, S. Moser

APL Materials· Volume 12· Issue 10

Abstract

We present a systematic growth study of epitaxial RuO2(110) and IrO2(110) on TiO2(110) substrates by pulsed laser deposition. We describe the main challenges encountered in the growth process, such as a deteriorating material flux due to laser-induced target metallization or the delicate balance of under- vs over-oxidation of the “stubborn” Ru and Ir metals. We identify growth temperatures and oxygen partial pressures of 700 K, 1 × 10−3 mbar for RuO2 and 770 K, 5 × 10−4 mbar for IrO2 to optimally balance between metal oxidation and particle mobility during nucleation. In contrast to IrO2, RuO2 exhibits layer-by-layer growth up to 5 unit cells if grown at high deposition rates. At low deposition rates, the large lattice mismatch between film and substrate fosters initial 3D island growth and cluster formation. In analogy to reports for RuO2 based on physical vapor deposition [He et al., J. Phys. Chem. C 119, 2692 (2015)], we find these islands to eventually merge and grow to continue in a step flow mode, resulting in highly crystalline, flat, stoichiometric films of RuO2(110) (up to 30 nm thickness) and IrO2(110) (up to 13 nm thickness) with well-defined line defects.
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Research context

OpenAlex topics: Electronic and Structural Properties of Oxides · Machine Learning in Materials Science · Semiconductor materials and devices

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Affiliations

Physikalisches Institut, Universität Würzburg 1 , 97074 Würzburg,

Würzburg-Dresden Cluster of Excellence ct.qmat, Universität Würzburg 2 , 97074 Würzburg,

Earth Resources and Materials, Institute of Geological and Nuclear Science 3 , 5010 Lower Hutt,

MacDiarmid Institute for Advanced Materials and Nanotechnology 4 , 6012 Wellington,

Röntgen Center for Complex Material Systems, Universität Würzburg 5 , 97074 Würzburg,

Funding

Deutsche Forschungsgemeinschaft · New Zealand Ministry of Business, Innovation and Employment

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