journal article·2014-06

Formation mechanism of barium calcium sulfoaluminate mineral

Shoude Wang, Yongbo Huang, Chenchen Gong, Lingchao Lu, Xin Cheng

Advances in Cement Research· Volume 26· Issue 3
Publisher page

Abstract

Barium calcium sulfoaluminate (C2·75B1·25A3S¯) mineral was prepared with analytical pure chemical reagents calcium carbonate, aluminium oxide, barium carbonate and barium sulfate. The sintering temperature and formation mechanism of the C2·75B1·25A3S¯ mineral were investigated by X-ray diffraction, differential scanning calorimetry/thermogravimetric analysis, scanning electron microscopy and infrared spectrometer analysis. The effect of iron (III) oxide on the C2·75B1·25A3S¯ mineral formation is discussed. The experimental results show that the beginning formation temperature, the large-amount formation temperature and decomposition temperature for C2·75B1·25A3S¯ mineral are 1100°C, 1350°C and 1370°C respectively. C2·75B1·25A3S¯ mineral is formed by solid reaction with 12CaO.7Al2O3 (C12A7), monocalcium aluminate (CA) or monobarium aluminate (BA) regarded as the interphase, as verified by variation of the Gibbs free energy of the reaction. An appropriate amount of iron (III) oxide can replace alumina to form iron-bearing C2·75B1·25A3S¯.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Chemical Synthesis and Characterization · Concrete and Cement Materials Research · X-ray Diffraction in Crystallography

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Associate Professor, Shandong Provincial Key Laboratory of Preparation and Measurement of Building Materials, University of Jinan, Jinan, China

Postgraduate student, Shandong Provincial Key Laboratory of Preparation and Measurement of Building Materials, University of Jinan, Jinan, China

Lecturer, Shandong Provincial Key Laboratory of Preparation and Measurement of Building Materials, University of Jinan, Jinan, China

Professor, Shandong Provincial Key Laboratory of Preparation and Measurement of Building Materials, University of Jinan, Jinan, China

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