journal article·2025-03-01

Feasibility of adding calcium hydroxide to FETNS–OPC: working performance, mechanical properties and reaction mechanism

Yanning Song, Hongxia Qiao, Qiong Feng, Chao Wei, Jianghua Zheng, Hongxia Qiao

Advances in Cement Research· Volume 37· Issue 3
Publisher page

Abstract

To solve the problem of low early-phase reactivity of ferrous extraction tailings of nickel slag (FETNS), the effects of calcium hydroxide (Ca(OH)2) as an alkali activator on the working performance, mechanical properties and hydration products of FETNS–ordinary Portland cement (OPC) composite cementitious systems were studied. The addition of calcium hydroxide was found to shorten the initial setting time by about 40% and the final setting time by about 20%. The compressive strength at 3, 7, 28 and 60 days was increased by 51.95%, 45.27%, 8.53% and 8.9%, respectively, with the addition of calcium hydroxide. Microstructural assessment (by scanning electron microscopy, X-ray diffraction, simultaneous thermal analysis, nitrogen adsorption test and low-field nuclear magnetic resonance analysis) showed that the incorporation of calcium hydroxide increased the reaction degree of the FETNS–OPC system, and more calcium silicate hydrate gel and ettringite were generated to fill internal pores, thus improving the compactness of the matrix. In summary, the incorporation of calcium hydroxide stimulated the early-phase reactivity of the composite system, promoted the formation of reaction products and optimised the internal pore structure.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Concrete and Cement Materials Research · Magnesium Oxide Properties and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

PhD student, School of Civil Engineering, Lanzhou University of Technology, Lanzhou, China

Professor, School of Civil Engineering, Lanzhou University of Technology, Lanzhou, China

Assistant Professor, School of Civil Engineering, Lanzhou University of Technology, Lanzhou, China

Post-graduate, School of Civil Engineering, Lanzhou University of Technology, Lanzhou, China

Senior Engineer, National Key Laboratory of Ni&Co Associated Minerals Resources Development and Comprehensive Utilization, Jinchang, China

Professor, Lanzhou University of Technology, Lanzhou, China (corresponding author: )

References (36)

Show source-provided references
1. 10.1016/j.conbuildmat.2018.10.11210.1016/j.conbuildmat.2018.10.112 ↗
2. 10.1016/j.scitotenv.2022.16070610.1016/j.scitotenv.2022.160706 ↗
3. 10.1016/j.conbuildmat.2015.09.03910.1016/j.conbuildmat.2015.09.039 ↗
4. 10.1016/j.jobe.2022.10561610.1016/j.jobe.2022.105616 ↗
5. Everett DH · 1958
6. 10.1007/s10971-007-1643-610.1007/s10971-007-1643-6 ↗
7. 10.1016/j.envint.2018.02.04510.1016/j.envint.2018.02.045 ↗
8. 10.1016/j.seppur.2015.10.05110.1016/j.seppur.2015.10.051 ↗
9. 10.1016/j.conbuildmat.2017.09.03810.1016/j.conbuildmat.2017.09.038 ↗
10. 10.1016/j.jece.2016.12.02010.1016/j.jece.2016.12.020 ↗
11. 10.1007/s12649-015-9346-710.1007/s12649-015-9346-7 ↗
12. 10.1016/j.conbuildmat.2019.02.16610.1016/j.conbuildmat.2019.02.166 ↗
13. 10.1016/j.conbuildmat.2015.02.04610.1016/j.conbuildmat.2015.02.046 ↗
14. 10.1016/j.jhazmat.2019.12093610.1016/j.jhazmat.2019.120936 ↗
15. 10.1016/j.conbuildmat.2021.12399110.1016/j.conbuildmat.2021.123991 ↗
16. 10.1016/j.mineng.2008.07.00310.1016/j.mineng.2008.07.003 ↗
17. 10.1063/1.171629610.1063/1.1716296 ↗
18. 10.1016/S1003-6326(13)62883-610.1016/S1003-6326(13)62883-6 ↗
19. 10.1016/j.cemconres.2015.04.01310.1016/j.cemconres.2015.04.013 ↗
20. 10.1016/j.conbuildmat.2017.02.02310.1016/j.conbuildmat.2017.02.023 ↗
21. SAC (Standardization Administration of China) (2005) GB/T12957-2005: General purpose slag cement, 1st edition. Standardization Administration of China, Beijing, PR China.
22. SAC (2007) GB175-2007: Common portland cement, 1st edition. Standardization Administration of China, Beijing, PR China.
23. SAC (2011) GB/T 1346-2011: Test methods for water requirement of normal consistency, setting time and soundness of the Portland cement, 1st edition. Standardization Administration of China, Beijing, PR China.
24. 10.1016/j.conbuildmat.2016.06.14410.1016/j.conbuildmat.2016.06.144 ↗
25. 10.1016/j.jclepro.2017.06.03510.1016/j.jclepro.2017.06.035 ↗
26. 10.1016/j.scp.2022.10070610.1016/j.scp.2022.100706 ↗
27. 10.1016/j.jece.2022.10792910.1016/j.jece.2022.107929 ↗
28. 10.1109/78.99505910.1109/78.995059 ↗
29. 10.1016/j.conbuildmat.2018.08.18210.1016/j.conbuildmat.2018.08.182 ↗
30. 10.1016/j.cemconres.2022.10676810.1016/j.cemconres.2022.106768 ↗
31. 10.1016/j.jobe.2022.10404610.1016/j.jobe.2022.104046 ↗
32. 10.1007/s11837-006-0209-310.1007/s11837-006-0209-3 ↗
33. 10.1016/j.conbuildmat.2018.10.10910.1016/j.conbuildmat.2018.10.109 ↗
34. 10.1016/j.resconrec.2018.08.00210.1016/j.resconrec.2018.08.002 ↗
35. 10.1016/j.conbuildmat.2020.12052310.1016/j.conbuildmat.2020.120523 ↗
36. 10.1007/s10973-021-10900-510.1007/s10973-021-10900-5 ↗