journal article·2014-11

Leaching behaviour of cementitious nuclear wasteforms containing caesium and strontium

W. Gashier, T. Miura, K. Hashimoto, R. J. Hand, H. Kinoshita

Advances in Applied Ceramics· Volume 113· Issue 8
Publisher page

Abstract

The leaching behaviour and physicochemical properties of cementitious nuclear wasteforms containing caesium and strontium waste simulants has been investigated. The cement wasteform consisted of a 9∶1 blend of blast furnace slag and ordinary Portland cement. Both non-loaded samples and samples that were waste loaded with 3 wt-% caesium and strontium added as nitrates have been studied. The cement hydration phases in the samples were identified, and the porosity and microstructure were analysed before leaching. The samples were leached for up to 6 months and the leached elements quantified. In the waste loaded cements, portlandite was not formed, and the monosulphate AFm phase appeared to be altered by the incorporation of the Sr(NO3)2. Incorporation of Cs and Sr also resulted in the increase in the leach rate of Ca2+.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Nuclear materials and radiation effects · Chemical Synthesis and Characterization · Concrete and Cement Materials Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (15)

Show source-provided references
1. Ojovan MI and Lee WE: ‘An introduction to nuclear waste immobilisation’; 2005, Oxford, Elsevier.10.1016/B978-008044462-8/50021-1 ↗
2. 10.1557/PROC-663-8910.1557/PROC-663-89 ↗
3. 10.1557/PROC-663-11510.1557/PROC-663-115 ↗
4. Aggarwal S, Angus MJ and Ketchen J: ‘Sorption of radionuclides onto specific mineral phases present in repository cements’, Report AEA Technology NSS/R312, 2000, 1–64.
5. 10.1016/j.jcis.2006.03.04310.1016/j.jcis.2006.03.043 ↗
6. 10.1021/es071227y10.1021/es071227y ↗
7. 10.1016/S0008-8846(00)00377-X10.1016/S0008-8846(00)00377-X ↗
8. 10.1016/0956-053X(92)90044-J10.1016/0956-053X(92)90044-J ↗
9. Maneva M and Petroff N: ‘Kinetics of dehydration and thermal decomposition of Sr(NO 3 ) 2 .4H 2 O and its deuterated analogue with a view to obtaining SrO’; Journal of Thermal Analysis, Vol.33 (1988), Springer, Netherlands, Akadémiai Kiadó.10.1007/BF01913922 ↗
10. Spence RD: ‘Chemistry and microstructure of solidified waste forms’; 1993, Lewis Publishers, USA.
11. Milestone NB · J. Aust. Ceram. Soc. · 2012 · 48 · 244
12. 10.1016/j.chemosphere.2007.09.01210.1016/j.chemosphere.2007.09.012 ↗
13. Balonis M: ‘The influence of inorganic chemical accelerators and corrosion inhibitors on the mineralogy of hydrated Portland cement systems’, PhD thesis, University of Aberdeen, Aberdeen, UK, 2010.10.1016/j.cemconres.2010.03.002 ↗
14. Crawford RW, Glasser FP, Rahman AA, Angus MJ and McCulloch CE: ‘Radioactive waste management and development of waste 6195’, 6, 195, The American Ceramic Society, USA 1971.
15. 10.1007/BF0290389310.1007/BF02903893 ↗