journal article·2018-08-18

Glass formation and properties of sodium zinc phosphate glasses doped with ferric oxide

Shangjiu Nian, Yin Zhang, Jun Li, Nianying Zhou, Wen Zou

Advances in Applied Ceramics· Volume 117· Issue 6
Publisher page

Abstract

Approximate glass-forming region of a P2O5–ZnO–Na2O (PZN) ternary system was investigated and determined. The properties of the glasses with ZnO contents between 35 and 50 mol-% were further investigated. When ZnO of 40P2O5–40ZnO–20Na2O glasses is replaced by 1–5 mol-% Fe2O3, respectively, the density, Tg and Tf increase first and then decrease, and they showed the maximum value of about 4 mol-% Fe2O3 replacement, while CTE and weight loss vary in opposite ways and showed the minimum value at about 4 mol-% Fe2O3 replacement. Structural studies were carried out by X-ray diffraction, infrared spectroscopy and Raman spectroscopy. With the increase in Fe2O3, the reduction of P=O bond is the main reason for the increase in water resistance of PZNF glass.
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Research context

OpenAlex topics: Glass properties and applications · Luminescence Properties of Advanced Materials · Pigment Synthesis and Properties

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Affiliations

School of Materials Science and Engineering, Nanjing Tech University, Nanjing, People’s Republic of China

Nanjing Haoqi Advanced Materials Co., Ltd., Nanjing, People’s Republic of China

Funding

Priority Academic Program Development of Jiangsu Higher Education Institutions · Jiangsu Collaborative Innovation Center for Advanced Inorganic Function Composites

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