Visible‐Light Photoreforming of Biomass Derivatives through MBi₂O₄‐P25 Heterostructures: Study of the Influence of Metals (M = Cu, Ni, Zn, Co)

Abstract In this work, MBi₂O₄‐P25 (M = Cu, Ni, Co, Zn) composites are successfully synthesized by a simple ball milling method by varying some parameters (rotation speed, rotation time, metal/TiO₂ ratio) to optimize the preparation conditions. The noble metal‐free TiO₂‐based photocatalysts are used to carry out the partial oxidation of glucose and glycerol with the simultaneous H₂ production under simulated solar light irradiation. Starting from glucose, 2.6 mmol of H₂ are obtained with a conversion of 34%, along with arabinose, formic acid and gluconic acid as main intermediates. By using glycerol, 3.2 mmol of H₂ are produced, with 17% conversion and the production of dihydroxyacetone and glycolic acid. The composites exhibit higher activity than pure P25 and CuBi₂O₄ (CBO). The produced H₂ amount is comparable to that reported in the literature by using Pt–TiO₂ photocatalysts. This study offers a paradigm for the future design of bifunctional photocatalysts for simultaneous noble metal‐free H₂ production and biomass valorization under environmentally friendly conditions with a possible scale up of the process.