journal article·2024-04Open access

GrafeoPlad Palladium: Insight on Structure and Activity of a New Catalyst Series of Broad Scope

Matteo Formenti, Maria Pia Casaletto, Giampaolo Barone, Mario Pagliaro, Cristina Della Pina, Valeria Butera, Rosaria Ciriminna

Advanced Sustainable Systems· Volume 8· Issue 4

Abstract

Abstract GrafeoPlad‐Pd, a new metal‐organic alloy comprised of Pd nanoparticles doped with 3D‐entrapped graphene oxide, has promising applicative potential in sustainable synthetic organic chemistry. Besides hydrogenation, the metal nanopowder comprising the material is also active and relatively stable in cross‐coupling reactions carried out consecutively. X‐ray photoelectron spectroscopy (XPS) surface investigation and density functional theory (DFT) calculations are applied to gain new insight into the structure and potential new catalytic activity of this new class of molecularly doped metals.
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Research context

OpenAlex topics: Nanomaterials for catalytic reactions · Nanocluster Synthesis and Applications · Catalytic Cross-Coupling Reactions

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Dipartimento di Chimica Università degli Studi di Milano via Golgi 19 20133 Milano Italy

Istituto per lo Studio dei Materiali Nanostrutturati CNR via U. La Malfa 153 90146 Palermo Italy

Dipartimento di Scienze e Tecnologie Biologiche Chimiche e Farmaceutiche Università degli Studi di Palermo v.le delle Scienze, Ed.17 90128 Palermo Italy

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