Depolymerization of Polyester and Polycarbonate Waste using HBpin and Cheap Zinc Catalysts
Source abstract
Abstract
Abstract This work describes a novel method for the efficient reductive depolymerization of polyester and polycarbonate plastic waste using pinacolborane (HBpin) catalyzed by Zn(OAc)2.2H2O and Zn(OTf)2. This method is applied to a variety of plastic waste and has the advantages of combining the use of non‐toxic, cheap, and commercially available catalysts with a mild, easy‐to‐handle reducing agent, with excellent yields, under mild reaction conditions.
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Research context
OpenAlex topics: Microplastics and Plastic Pollution · biodegradable polymer synthesis and properties · Recycling and Waste Management Techniques
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Affiliations
Centro de Química Estrutural Institute of Molecular Sciences Departamento de Engenharia Química Instituto Superior Técnico Universidade de Lisboa Av. Rovisco Pais Lisboa 1049‐001 Portugal
References (43)
Show source-provided references
1. 10.1016/j.scitotenv.2022.15490710.1016/j.scitotenv.2022.154907 ↗
2. 10.1016/j.envint.2022.10719910.1016/j.envint.2022.107199 ↗
3. 10.7326/M19-061810.7326/M19-0618 ↗
4. 10.3390/polym1413270010.3390/polym14132700 ↗
5. 10.3390/polym1415313310.3390/polym14153133 ↗
6. 10.1002/cssc.20220052210.1002/cssc.202200522 ↗
7. 10.1038/s41929-021-00648-410.1038/s41929-021-00648-4 ↗
8. 10.1002/cssc.20210087410.1002/cssc.202100874 ↗
9. 10.3390/ma1417478210.3390/ma14174782 ↗
10. 10.1016/j.xcrp.2021.10051410.1016/j.xcrp.2021.100514 ↗
11. 10.1002/cssc.20210163110.1002/cssc.202101631 ↗
12. 10.1002/cssc.20210065210.1002/cssc.202100652 ↗
13. 10.1002/cssc.20210075210.1002/cssc.202100752 ↗
14. 10.1002/cssc.20200266610.1002/cssc.202002666 ↗
15. 10.3762/bjoc.17.5310.3762/bjoc.17.53 ↗
16. 10.1002/cssc.20210090410.1002/cssc.202100904 ↗
17. 10.1002/cssc.20200190510.1002/cssc.202001905 ↗
18. 10.1039/D0GC01252A10.1039/D0GC01252A ↗
19. 10.3390/suschem101000110.3390/suschem1010001 ↗
20. 10.1039/C8PY01284A10.1039/C8PY01284A ↗
21. 10.1016/j.chempr.2018.10.01110.1016/j.chempr.2018.10.011 ↗
22. 10.1039/C7GC01496A10.1039/C7GC01496A ↗
23. 10.1039/C4GC01760A10.1039/C4GC01760A ↗
24. 10.1039/D1GC01634B10.1039/D1GC01634B ↗
25. 10.1039/c4cc00541d10.1039/c4cc00541d ↗
26. 10.1002/chem.20150090710.1002/chem.201500907 ↗
27. 10.1126/sciadv.aat966910.1126/sciadv.aat9669 ↗
28. 10.1021/acssuschemeng.8b0184210.1021/acssuschemeng.8b01842 ↗
29. 10.1039/D2CC00184E10.1039/D2CC00184E ↗
30. 10.1039/D2GC02186B10.1039/D2GC02186B ↗
31. 10.1002/cssc.20150005410.1002/cssc.201500054 ↗
32. 10.1039/C9GC04206G10.1039/C9GC04206G ↗
33. 10.3390/catal1204038110.3390/catal12040381 ↗
34. 10.1016/j.mcat.2023.11312810.1016/j.mcat.2023.113128 ↗
35. 10.1002/chem.20110080010.1002/chem.201100800 ↗
36. 10.1038/s41557-021-00715-010.1038/s41557-021-00715-0 ↗
37. 10.1039/D2NJ03136A10.1039/D2NJ03136A ↗
38. 10.1002/cssc.20210013010.1002/cssc.202100130 ↗
39. 10.1039/C7CS00171A10.1039/C7CS00171A ↗
40. 10.1016/j.ccr.2013.10.01710.1016/j.ccr.2013.10.017 ↗
41. 10.3390/ijms23201267910.3390/ijms232012679 ↗
42. 10.1021/acscatal.9b0137010.1021/acscatal.9b01370 ↗
43. 10.1021/acs.joc.0c0128510.1021/acs.joc.0c01285 ↗