High Temperature Polymer Electrolyte Membrane Fuel Cells for Integrated Fuel Cell – Methanol Reformer Power Systems: A Critical Review

Abstract The development of reliable power sources is important for the continuous operation of various electric equipment in unmanned aircraft and the field environment. Currently electric power delivery to such systems is mainly by battery packs. An alternative is to use fuel cells (FCs). FCs are electrochemical devices that are used to convert chemical energy of fuels such as hydrogen and methanol to electricity. Methanol is an attractive fuel because it is liquid at ambient temperature, has a much higher energy density than hydrogen and low reforming temperature (220–300 °C). Thus, integration of methanol steam reformers (MSRs) with FCs makes it possible to continuously produce electricity. The key challenge in such power system is the development of fuel cells which can be effectively operated at compatible temperature range of MSR, i.e., 220–300 °C in order to increase synergetic heat integration and system reliability. Herein, the latest development of high temperature polymer electrolyte membrane fuel cells (HT‐PEMFCs) is critically reviewed. The prospect of the integrated HT‐PEMFCs‐MSR as a reliable and compact power source is discussed. The results indicate that phosphoric acid doped polybenzimidazole (PA/PBI) membranes with in situ formed phosphosilicate nanocluster proton carriers show the technical feasibility of the development of HT‐PEMFCs at temperatures of 200–300 °C.