journal article·2023-02

Precise Molecular Design for Two Parent BN‐Pentacyclic Isomers Through Stitching Engineering Toward Extremely Sensitive Explosive Detection (Advanced Optical Materials 3/2023)

Huanan Huang, Junxiong Yao, Han Xu, Jiaqi Li, Hanbin Wang, Cheng Xiong, Binhua Fang, Yawei Wang, Ying Zhou, Xiaohua Cao, Jianguo Wang, Ben Zhong Tang

Advanced Optical Materials· Volume 11· Issue 3
Publisher page

Abstract

The boron-nitrogen (BN) aromatic compounds represent a unique hybrid system and display attractive photophysical and chemical properties. In article number 2202433, Huanan Huang, Jianguo Wang, Ben Zhong Tang, and co-workers design two BN-pentacyclic isomers through stitching engineering. Systematic research revealed that the crystal structure, aromaticity and photophysical properties vary with the change of BN embedded patterns, indicating that precise control of stitching pattern is of great importance to effectively modulate molecular properties. Such a discovery vastly extends knowledge of the structure and functionality of BN-doped polycyclic aromatic hydrocarbons, making them very encouraging in the materials chemistry field.
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Research context

OpenAlex topics: Luminescence and Fluorescent Materials · Molecular Sensors and Ion Detection · Polydiacetylene-based materials and applications

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Affiliations

College of Chemistry and Chemical Engineering Jiangxi Province Engineering Research Center of Ecological Chemical Industry Jiujiang Key Laboratory of Organosilicon Chemistry and Application Jiujiang University Jiujiang 332005 China

College of Chemistry and Chemical Engineering Inner Mongolia Key Laboratory of Fine Organic Synthesis Inner Mongolia University Hohhot 010021 China

Shenzhen Institute of Aggregate Science and Technology School of Science and Engineering The Chinese University of Hong Kong Shenzhen 518172 China

References

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