Processing‐Dependent Microstructure of AgCl–CsAgCl₂ Eutectic Photonic Crystals

Abstract Directional solidification of a eutectic melt allows control over the resultant eutectic microstructure, which in turn impacts both the mechanical and optical properties of the material. These self‐organized phase‐separated eutectic materials can be tuned to have periodicities from tens of micrometers down to nanometers. Furthermore, the two phases possess differences in their refractive index leading to interesting optical properties that can be tailored within the visible to infrared wavelength regime. It is found the binary salt eutectic AgCl–CsAgCl₂ system forms a rod microstructure with sample draw rates up to 0.2 mm s⁻¹ which transitions to a lamellar microstructure at draw rates greater than 0.36 mm s⁻¹. Heat‐transfer simulations reveal a draw rate‐dependent direction of motion of the solidification front, which for a range of draw rates requires nucleation of the minority solid phase at the sample wall. Phase‐field modeling indicates that the initial eutectic structure at the sample boundary, either rod or lamellar, dictates the bulk eutectic morphology. These samples contain submicrometer periodicities which coupled with their optical transparency results in them exhibiting draw rate‐dependent near‐IR reflectance peaks consistent with stop bands for 2D hexagonal (rod) and 1D planar (lamellar) photonic crystals.