Magnetophotoluminescence Response Triggered by the Triplet State in Metallofullerene

Chaofeng Zheng; Guixian Li; Jiayi Liang; Lu Yu; Wang Li; Yibo Han; Chunru Wang; Taishan Wang

doi:10.1002/adom.202303334

journal article·2024-06

Magnetophotoluminescence Response Triggered by the Triplet State in Metallofullerene

Chaofeng Zheng, Guixian Li, Jiayi Liang, Lu Yu, Wang Li, Yibo Han, Chunru Wang, Taishan Wang

Advanced Optical Materials· Volume 12· Issue 17

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Abstract

Abstract This paper reports the discovery of a magnetophotoluminescence response in metallofullerene Y₃N@C₈₀ triggered by the triplet excited state. In experiments, Y₃N@C₈₀ exhibits magnetic field‐dependent (0→±42 T) phosphorescence emission at 4.2 K. Crucially, with increasing magnetic field, the phosphorescence peaks shift to longer wavelengths owing to the Zeeman effect. Further, a nanoring of [9]CPPH is employed to modulate the magnetophotoluminescence response of Y₃N@C₈₀ through host−guest interaction. The circularly polarized phosphorescence spectra of Y₃N@C₈₀ and Y₃N@C₈₀⊂[9]CPPH are investigated to further reveal their magnetophotoluminescence properties using the technique of field‐induced circular polarization (FICPO). These results show that metallofullerene Y₃N@C₈₀ with magnetophotoluminescence response has potential applications in spin‐related optical devices and quantum technology.

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Research context

Nanomaterials

OpenAlex topics: Quantum optics and atomic interactions · Fullerene Chemistry and Applications · Photoreceptor and optogenetics research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Beijing National Laboratory for Molecular Sciences Key Laboratory of Molecular Nanostructure and Nanotechnology Institute of Chemistry Chinese Academy of Sciences Beijing 100190 China

University of Chinese Academy of Sciences Beijing 100049 China

Wuhan National High Magnetic Field Center and School of Physics Huazhong University of Science and Technology Wuhan 430074 China

High Magnetic Field Laboratory Chinese Academy of Science Hefei Anhui 230031 China

MOE Key Laboratory of Cluster Science School of Chemistry and Chemical Engineering Beijing Institute of Technology Beijing 102488 China

Funding

National Natural Science Foundation of China · Youth Innovation Promotion Association of the Chinese Academy of Sciences · National Basic Research Program of China

References (37)

Show source-provided references

1. 10.1002/adma.20200329710.1002/adma.202003297 ↗

2. 10.1038/s41566-020-00718-210.1038/s41566-020-00718-2 ↗

3. 10.1080/00018732.2019.159029510.1080/00018732.2019.1590295 ↗

4. 10.1016/0301-0104(89)87092-210.1016/0301-0104(89)87092-2 ↗

5. 10.1002/adma.20200822510.1002/adma.202008225 ↗

6. 10.1103/RevModPhys.76.32310.1103/RevModPhys.76.323 ↗

7. 10.1126/science.125965510.1126/science.1259655 ↗

8. 10.1126/science.123724210.1126/science.1237242 ↗

9. 10.1103/PhysRevB.43.415210.1103/PhysRevB.43.4152 ↗

10. 10.1103/PhysRevB.50.447610.1103/PhysRevB.50.4476 ↗

11. 10.1038/ncomms1064310.1038/ncomms10643 ↗

12. 10.1021/jacs.0c0898610.1021/jacs.0c08986 ↗

13. 10.1021/acscentsci.0c0073710.1021/acscentsci.0c00737 ↗

14. 10.1038/s41557-019-0232-y10.1038/s41557-019-0232-y ↗

15. 10.1038/s41586-020-1976-710.1038/s41586-020-1976-7 ↗

16. 10.1002/adom.20220247710.1002/adom.202202477 ↗

17. 10.1038/nature0712810.1038/nature07128 ↗

18. Bayliss S. L. · Phys. Rev. X · 2022 · 12

19. 10.1021/j100166a01110.1021/j100166a011 ↗

20. 10.1039/C8CC07939K10.1039/C8CC07939K ↗

21. 10.1038/s41570-020-0200-510.1038/s41570-020-0200-5 ↗

22. 10.1038/nature0881210.1038/nature08812 ↗

23. 10.1038/s41566-018-0232-210.1038/s41566-018-0232-2 ↗

24. 10.1021/jacs.1c0066110.1021/jacs.1c00661 ↗

25. 10.1063/1.214726210.1063/1.2147262 ↗

26. 10.1126/science.aav261610.1126/science.aav2616 ↗

27. 10.1103/PhysRevB.82.03341010.1103/PhysRevB.82.033410 ↗

28. 10.1038/s41534-021-00362-w10.1038/s41534-021-00362-w ↗

29. 10.1002/anie.20171063710.1002/anie.201710637 ↗

30. 10.1039/D0SC07045A10.1039/D0SC07045A ↗

31. 10.1021/acsnano.1c0510510.1021/acsnano.1c05105 ↗

32. 10.1016/B978-0-12-803581-8.09584-910.1016/B978-0-12-803581-8.09584-9 ↗

33. 10.1021/acs.jpcc.9b0245110.1021/acs.jpcc.9b02451 ↗

34. 10.1039/D0CP05775D10.1039/D0CP05775D ↗

35. 10.1103/PhysRevB.88.03530210.1103/PhysRevB.88.035302 ↗

36. 10.1021/acs.nanolett.7b0282710.1021/acs.nanolett.7b02827 ↗

37. 10.1002/ejoc.20210149310.1002/ejoc.202101493 ↗