DataVXAdvanced Optical MaterialsPaper
journal article·2023-02Open access

Tunable and Thermally Stable Luminescence from Polycyclic Aromatic Hydrocarbons Confined in a Zeolitic Imidazolate Framework

Min Tu, Flip de Jong, Cristina Martín, Helge Reinsch, Sabina Rodríguez‐Hermida, Arne Meulemans, Eduard Fron, Daniel Escudero, Mark Van der Auweraer, Johan Hofkens, Rob Ameloot

Advanced Optical Materials· Volume 11· Issue 3
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Source abstract

Abstract

Abstract Metal–organic frameworks (MOFs) can provide a variety of nanocompartments for the confinement of guest molecules. Furthermore, the emissions of fluorescent molecules can be tuned by confinement. In this study, a solvent‐free “bottle‐around‐ship” method is used to encapsulate perylene and 9,10‐dimethylanthracene, two polycyclic aromatic hydrocarbons, in the MOF ZIF‐8. Luminescence color tuning is achieved, including white‐light emission, when controlling the loading of only a single type of guest. Photophysical analysis suggests that the variations in luminescence result from various guest arrangements in the nanocompartments, as well as host–guest interactions. Because of the tight confinement of the guests, this host–guest system displays excellent luminescence thermal stability.
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Research context

Nanomaterials

OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Luminescence and Fluorescent Materials · Lanthanide and Transition Metal Complexes

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

2020 X‐Lab Shanghai Institute of Microsystem and Information Technology Chinese Academy of Sciences Changning Road 865 Shanghai 200050 China

Centre for Membrane Separations Adsorption Catalysis and Spectroscopy (cMACS) KU Leuven Celestijnenlaan 200F Leuven 3001 Belgium

Division of Molecular Imaging and Photonics Department of Chemistry KU Leuven Celestijnenlaan 200F Leuven 3001 Belgium

Institut für Anorganische Chemie Christian‐Albrechts‐Universität Kiel Christian‐Albrechts‐Platz 4 24118 Kiel Germany

Division of Quantum Chemistry and Physical Chemistry Department of Chemistry KU Leuven Celestijnenlaan 200F Leuven 3001 Belgium

KU Leuven Core Facility for Advanced Spectroscopy KU Leuven Celestijnenlaan 200F Leuven 3001 Belgium

Funding

KU Leuven

References (48)

Show source-provided references
1. 10.1002/adfm.20030100510.1002/adfm.200301005 ↗
2. 10.1002/adma.20090214810.1002/adma.200902148 ↗
3. 10.1016/j.mser.2010.07.00110.1016/j.mser.2010.07.001 ↗
4. 10.1002/adma.20050072710.1002/adma.200500727 ↗
5. 10.1021/acsenergylett.7b0076510.1021/acsenergylett.7b00765 ↗
6. 10.1002/adom.20200181710.1002/adom.202001817 ↗
7. 10.1021/nn303217q10.1021/nn303217q ↗
8. 10.1038/nmat484310.1038/nmat4843 ↗
9. 10.1021/acs.chemmater.8b0530010.1021/acs.chemmater.8b05300 ↗
10. 10.1039/C3CS60314H10.1039/C3CS60314H ↗
11. 10.1021/jacs.6b0477610.1021/jacs.6b04776 ↗
12. 10.1039/D1TC02952E10.1039/D1TC02952E ↗
13. 10.1021/cr200101d10.1021/cr200101d ↗
14. 10.1016/j.micromeso.2015.03.03610.1016/j.micromeso.2015.03.036 ↗
15. 10.1039/C6CS00930A10.1039/C6CS00930A ↗
16. 10.1039/C7CS00879A10.1039/C7CS00879A ↗
17. 10.1021/acs.chemrev.8b0022210.1021/acs.chemrev.8b00222 ↗
18. 10.1021/acs.accounts.9b0057510.1021/acs.accounts.9b00575 ↗
19. 10.1002/adma.20180689710.1002/adma.201806897 ↗
20. 10.1002/anie.20181399610.1002/anie.201813996 ↗
21. 10.1021/acssensors.0c0256210.1021/acssensors.0c02562 ↗
22. 10.1039/D0CS01519A10.1039/D0CS01519A ↗
23. 10.1021/acs.chemrev.1c0098010.1021/acs.chemrev.1c00980 ↗
24. 10.1002/adfm.20150175610.1002/adfm.201501756 ↗
25. 10.1039/C5CC08703A10.1039/C5CC08703A ↗
26. 10.1002/adma.20170077810.1002/adma.201700778 ↗
27. 10.1021/acsami.8b0493710.1021/acsami.8b04937 ↗
28. 10.1002/adom.20180096810.1002/adom.201800968 ↗
29. 10.1039/C8TC05956J10.1039/C8TC05956J ↗
30. 10.1021/acs.chemmater.8b0412610.1021/acs.chemmater.8b04126 ↗
31. 10.1039/C9CC05533A10.1039/C9CC05533A ↗
32. 10.1021/jacs.9b0723610.1021/jacs.9b07236 ↗
33. 10.1021/acsanm.1c0182910.1021/acsanm.1c01829 ↗
34. 10.1016/j.poly.2018.07.04310.1016/j.poly.2018.07.043 ↗
35. 10.1002/anie.20150358810.1002/anie.201503588 ↗
36. 10.1021/jp807684m10.1021/jp807684m ↗
37. Polycycl. Aromat. Compd. · 2006 · 2 · 75
38. 10.1073/pnas.060243910310.1073/pnas.0602439103 ↗
39. 10.1002/anie.20050377810.1002/anie.200503778 ↗
40. 10.1038/nmat450910.1038/nmat4509 ↗
41. 10.1021/acs.chemmater.9b0380710.1021/acs.chemmater.9b03807 ↗
42. 10.1016/S1010-6030(01)00562-710.1016/S1010-6030(01)00562-7 ↗
43. 10.1016/0009-2614(82)80303-510.1016/0009-2614(82)80303-5 ↗
44. 10.1016/1010-6030(93)80123-Q10.1016/1010-6030(93)80123-Q ↗
45. 10.1098/rspa.1966.011510.1098/rspa.1966.0115 ↗
46. 10.1063/1.172737110.1063/1.1727371 ↗
47. 10.1016/j.jphotochem.2017.08.03010.1016/j.jphotochem.2017.08.030 ↗
48. Birks J. · 1970