Multi‐Level Optical Switching by Amorphization in Single‐ and Multi‐Phase Change Material Structures

Abstract The optical properties of phase‐change materials (PCMs) can be tuned to multiple levels by controlling the transition between their amorphous and crystalline phases. In multi‐material PCM structures, the number of discrete reflectance levels can be increased according to the number of PCM layers. However, the effect of increasing the number of layers on quenching and reversibility has not been thoroughly studied. In this work, the phase‐change physics and thermal conditions required for reversible switching of single and multi‐material PCM switches are discussed based on thermo‐optical phase‐change models and laser switching experiments. By using nanosecond laser pulses, 16 different reflectance levels in Ge₂Sb₂Te₅ are demonstrated via amorphization. Furthermore, a multi‐material switch based on Ge₂Sb₂Te₅ and GeTe with four discrete reflectance levels is experimentally proven with a reversible multi‐level response. The results and design principles presented herein will impact active photonics applications that rely on dynamic multi‐level operation, such as optical computing, beam steering, and next‐generation display technologies.