Periodically Aligned Dye Molecules Integrated in a Single MOF Microcrystal Exhibit Single‐Mode Linearly Polarized Lasing

Huajun He; En Ma; Jiancan Yu; Yuanjing Cui; Yuankun Lin; Yu Yang; Xueyuan Chen; Banglin Chen; Guodong Qian

doi:10.1002/adom.201601040

journal article·2017-05

Periodically Aligned Dye Molecules Integrated in a Single MOF Microcrystal Exhibit Single‐Mode Linearly Polarized Lasing

Huajun He, En Ma, Jiancan Yu, Yuanjing Cui, Yuankun Lin, Yu Yang, Xueyuan Chen, Banglin Chen, Guodong Qian

Advanced Optical Materials· Volume 5· Issue 10

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Source abstract

Abstract

Due to the periodically physical/chemical environment and high‐efficient confinement effect of the metal‐organic framework (MOF) only possessing 1D channels, the authors realize periodically and highly aligned dye molecule integration within the MOF hybrid material ZJU‐68⊃DMASM. Such molecule integration can provide an opportunity to directly determine 4‐[p‐(dimethylamino)styryl]‐1‐methylpyridinium (DMASM) molecules in the MOF channels by electron density mapping using X‐ray diffraction data. Furthermore, combining the anisotropic emission property of such molecule integration and the perfect crystal morphology of ZJU‐68 serving as the natural resonant cavity, the authors obtain a single‐mode linearly polarized laser excited by light ranging from visible to near‐infrared.

Source: crossref · Quality: baseline

Research context

OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Magnetism in coordination complexes · Luminescence and Fluorescent Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

State Key Laboratory of Silicon Materials Cyrus Tang Center for Sensor Materials and Applications School of Materials Science and Engineering Zhejiang University Hangzhou 310027 China

Xiamen Institute of Rare Earth Materials Chinese Academy of Sciences Xiamen Fujian 361021 China

CAS Key Laboratory of Design and Assembly of Functional Nanostructures Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou Fujian 350002 China

Department of Physics University of North Texas Denton TX 76203 USA

Department of Chemistry University of Texas at San Antonio San Antonio TX 78249 USA

Funding

National Natural Science Foundation of China · Natural Science Foundation of Zhejiang Province · Welch Foundation · National Science Foundation

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