Reversible Photochromism for Dynamically Tuning Full‐Color Circularly Polarized Luminescence Toward Multi‐Level Anti‐Counterfeiting Application

Abstract Photochromic circularly polarized luminescence (CPL) demonstrates broad application prospects in the field of advanced functional materials. However, the current photochromic CPL focuses predominantly on single‐band CPL adjustment, and how to achieve dynamically tunable CPL in multi‐band is still highly challenging. This work reports the success in utilizing reversible photochromism for realizing full‐color CPL emission. Photochromic flexible films are created consisting of triple components: spiropyran (SP) working as photochromic matter, polyurethane (PU) as matrix, and chiral helical polyacetylene as chiral component. Further introducing blue fluorophore 9‐anthracene carboxylic acid (ACA) in the film, blue CPL and red CPL are emitted respectively through selective absorption/transmission and circularly polarized fluorescence energy transfer (CPF‐ET). Doping the photochromic film with diverse fluorophores provides full‐color CPL emission. Adding Zn²⁺ further intensifies fluorescence and CPL via forming merocyanine (MC)‐Zn²⁺ complex. Taking advantage of the diverse fluorescence and CPL emission, anti‐counterfeiting, and secondary encryption application of the resulting photochromic CPL materials are demonstrated.