journal article·2021-10Open access

Detection of X‐Ray Doses with Color‐Changing Hackmanites: Mechanism and Application

Sami Vuori, Pauline Colinet, Isabella Norrbo, Ralph Steininger, Timo Saarinen, Heikki Palonen, Petriina Paturi, Lucas C. V. Rodrigues, Jörg Göttlicher, Tangui Le Bahers, Mika Lastusaari

Advanced Optical Materials· Volume 9· Issue 20

Abstract

Abstract Hackmanites, a variety of sodalite with the general formula Na8Al6Si6O24(Cl,S)2, are a family of nature‐based smart materials having the ability for reversible photochromism upon UV or X‐ray exposure. Being nontoxic, cheap, and durable, hackmanite would be an optimal material for the visual detection of the presence of X‐rays in simple portable systems. However, its X‐ray‐induced coloring abilities are so far known only qualitatively. In this work, a combination of experimental and computational methods is used to reveal the mechanism of X‐ray‐induced color changing in these materials. Finally, their use is demonstrated both in color intensity‐based X‐ray dosimetry and photochromic X‐ray imaging.
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Research context

OpenAlex topics: Luminescence Properties of Advanced Materials · Advanced Photocatalysis Techniques · Pigment Synthesis and Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemistry University of Turku Turku FI‐20014 Finland

Doctoral Programme in Physical and Chemical Sciences University of Turku Graduate School (UTUGS) Turku FI‐20014 Finland

Laboratoire de Chimie (UMR 5182) Univ Lyon ENS de Lyon CNRS Université Lyon 1 Lyon F‐69364 France

Karlsruhe Institute of Technology DE‐76131 Karlsruhe Germany

Department of Geography and Geology University of Turku Turku FI‐20014 Finland

Wihuri Physical Laboratory Department of Physics and Astronomy University of Turku Turku FI‐20014 Finland

Department of Fundamental Chemistry Institute of Chemistry University of São Paulo São Paulo SP 05508‐000 Brazil

Funding

Business Finland · Agence Nationale de la Recherche

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