journal article·2021-02Open access

Electroconvection in Zwitterion‐Doped Nematic Liquid Crystals and Application as Smart Windows

Yi Zhang, Xiulan Yang, Yuanyuan Zhan, Yang Zhang, Jialin He, Pengrong Lv, Dong Yuan, Xiaowen Hu, Danqing Liu, Dirk Jan Broer, Guofu Zhou, Wei Zhao

Advanced Optical Materials· Volume 9· Issue 3

Abstract

Abstract Electroconvection (EC) in liquid crystals (LCs) is extensively studied for the formation of regular nonequilibrium structures, and the applications that require strong light scattering and high haze. Doping the LCs with ionic species has proven to be an effective method to obtain uniform and high‐quality textures. Herein, zwitterion is explored as a new class of ionic dopant that has little problem of ion accumulation as compared to typical organic electrolytes. A rich variety of EC patterns are observed and characterized for both positive and negative LCs doped with a zwitterion Reichardt's dye. The initial homogeneous or homeotropic alignment, as well as the voltage and frequency of the applied electric field, is shown to influence the formation of EC patterns, among which the dynamic scattering mode (DSM) is specially examined for the application as privacy‐protecting smart windows. Using an LC mixture doped with zwitterions, the smart window demonstrates outstanding performance, as well as much improved durability for a wide range of operating conditions. Such a method offers a simple strategy for the fabrication of polymer‐free smart windows.
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Research context

OpenAlex topics: Liquid Crystal Research Advancements · Nonlinear Dynamics and Pattern Formation · Photonic Crystals and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

SCNU‐TUE Joint Lab of Device Integrated Responsive Materials (DIRM) National Center for International Research on Green Optoelectronics South China Normal University No 378, West Waihuan Road, Guangzhou Higher Education Mega Center Guangzhou 510006 P. R. China

Solar Energy Research Institute Yunnan Normal University Kunming 650500 P. R. China

Guangdong Provincial Key Laboratory of Optical Information Materials and Technology & Institute of Electronic Paper Displays South China Academy of Advanced Optoelectronics South China Normal University Guangzhou 510006 P. R. China

Stimuli‐Responsive Functional Materials and Devices Department of Chemical Engineering and Chemistry Eindhoven University of Technology Den Dolech 2 Eindhoven MB 5600 The Netherlands

Shenzhen Guohua Optoelectronics Tech. Co., Ltd. Shenzhen 518110 P. R. China

Funding

National Basic Research Program of China · Higher Education Discipline Innovation Project

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