Efficient Blue Thermally Activated Delayed Fluorescence Molecules with Sandwich‐Structured Through‐Space Charge Transfer for Fabricating High‐Performance OLEDs

Abstract Exploring robust blue luminescent materials is of high significance but challenging for the commercialization application of organic light‐emitting diodes (OLEDs). In this work, it is wished to report two blue thermally activated delayed fluorescence (TADF) molecules with a through‐space charge transfer feature. They have sandwich‐structured molecular backbones comprised of one triphenyltriazine acceptor and two 9‐phenylcarbazole or 3,6‐di(tert‐butyl)‐9‐phenylcarbazole donors that are linked at the 1,8,9‐positions of a 3,6‐di(tert‐butyl)carbazole holder, and exhibit high thermal stability and strong blue delayed fluorescence with high photoluminescence quantum yields and fast reverse intersystem crossing. The blue OLEDs use 2TBCTC as an emitter and provide outstanding maximum external quantum efficiencies (EQE_maxs) of up to 32.76% with Commission Internationale de I'Eclairage coordinates of (0.160, 0.206). To the best of knowledge, 2TBCTC is the most efficient blue TADF emitter based on through‐space charge transfer in the literature. Moreover, the interlayer‐sensitizing OLED employs 2TBCTC as a sensitizer for blue multi‐resonance TADF (MR‐TADF) molecule (v‐DABNA) as guest emitter attains an excellent EQE_max of 32.69% with a narrow full width at half maximum of 18 nm, validating the excellent potential of 2TBCTC as sensitizer for MR‐TADF emitters and the feasibility and effectiveness of the interlayer sensitization strategy for blue hyperfluorescence OLEDs.