Hafnium Sulfide Nanosheets for Ultrafast Photonic Device

Abstract Group IVB transition metal dichalcogenides (TMDs) have attracted significant interests in photoelectronics due to their predictable superior physical properties compared to group VIB (Mo and W) TMDs. However, the nonlinear optical properties and ultrafast photonic devices based on group IVB TMDs remained unexplored so far. Herein, the nonlinear optical absorption of HfS₂ nanosheets (NSs) prepared by liquid exfoliation is demonstrated. The usage of HfS₂ as a new ultrafast photonic device for high‐energy and ultrashort pulse generation in a fiber laser is reported for the first time. A photonic crystal fiber (PCF) assisted deposition method is presented for the fabrication of an HfS₂‐microfiber integrated saturable absorber (SA) device with precisely controllable light–matter interaction, which can benefit the output of the device. The HfS₂‐microfiber SA device shows modulation depth of 15.7% and exhibits outstanding ultrashort pulse generation performance with pulse duration of 221.7 fs in the communication band. The experimental results suggest that HfS₂ presents highly nonlinear optical absorption and can be developed into an excellent candidate of SA devices for the development of HfS₂‐based ultrafast photonics.