Microwave Investigation of DMSO‐Doped PEDOT:PSS Patch Resonators Under Varying Relative Humidity

Abstract Poly(3,4‐ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) is a conductive polymer widely used in various microwave sensing components. Enhancing the efficiency of PEDOT:PSS‐based microwave structures relies on improving the polymer's conductivity, achievable by adding secondary solvents such as dimethyl sulfoxide (DMSO), which significantly boosts the electrical conductivity. However, the performance of DMSO‐doped PEDOT:PSS films in microwave regime requires investigations. Herein, patch resonators are fabricated using solution processing of aqueous dispersion of PEDOT:PSS doped with varying concentrations of DMSO from 0 to 8 wt.% to investigate their microwave behavior within the frequency range of 4.5–6.5 GHz. The PEDOT:PSS patch structures are implemented on a glass substrate and their resonant characteristics, including resonant frequency and amplitude, are studied in response to varying relative humidity (RH) levels ranging from 0% to 70%. The significant variations in the microwave responses are observed at the resonant amplitude, confirming the main impact of humidity on the conductivity of the films. According to the measured results, the 2 wt.% doped patch shows greater sensitivity to the changes to the RH in contrast to the 8 wt.% doped patches, where the response shows less sensitivity to the humidity variation. The results indicate that a lower percentage of DMSO enhances sensitivity to the humidity at the cost of increased electromagnetic loss in the resonant patch structures for humidity sensing applications.