Dry‐Wet Hybrid Direct Printing of Laser‐Induced Graphene and Zinc Oxide Nanoribbons for Continuous‐Flow Manufacturing of Flexible Wearable Photodetectors

Abstract Flexible wearable electronics enable an in situ and real‐time measurement of human physiology and micro‐environment. Although large‐scale production of flexible wearable electronics is demonstrated using direct printing techniques, the “wet” nature of these techniques requires multiple procedures and chemicals to prepare printable inks, increasing the complexity and cost. Here, a dry‐wet hybrid direct printing is developed for the mass production of flexible wearable photodetectors, in which a “dry” direct laser writing and a “wet” screen printing are employed to fabricate laser‐induced graphene as electrode layer and zinc oxide as photosensitive layer, respectively. The liquid‐free fabrication of LIG significantly reduces the complexity and cost of the production. An automatic conveyor belt is designed to realize continuous‐flow manufacturing. The photodetectors demonstrate good ultraviolet (UV) photodetection performances, such as a photo‐to‐dark current ratio (I_photo/I_dark) of 5.67 × 10⁵, approaching the record of similar devices. The manufacturing system presents a high reproducibility, considering that I_photo/I_dark only fluctuates within 7.10%. The flexible photodetectors are worn as wristbands after being integrated with a data acquisition and transmission circuit. UV intensity is real‐time monitored on a self‐developed mobile application. The continuous‐flow manufacturing based on the developed dry‐wet hybrid direct printing sheds light on the mass production of flexible wearable electronics.