Electrically Conductive, Reduced Graphene Oxide Structures Fabricated by Inkjet Printing and Low Temperature Plasma Reduction

Abstract Here, an environmentally‐friendly and scalable process is reported to synthesize reduced graphene oxide (RGO) thin films for printed electronics applications. The films are produced by inkjet printing GO flakes dispersed binder‐free in aqueous solutions followed by treatment with a nonthermal, radio‐frequency (RF) plasma containing only argon (Ar) gas. The plasma process is found to heat the substrate to temperatures no greater than 138 °C, enabling RGO to be printed directly on a wide range of temperature‐sensitive substrate materials including photo paper. Unlike other low‐temperature methods such as electrochemical reduction, plasma reduction is friendly to moisture absorbent materials. Moreover, the plasma treatment can be performed on nonconducting substrates, eliminating the need for film transfer. From an applications perspective, the printed, plasma‐reduced RGO exhibits excellent electrical, mechanical, and electrochemical properties. As a technology demonstrator, the working electrodes of hydrogen peroxide (H₂O₂) sensors fabricated from plasma‐reduced GO show a sensitivity of 277 ± 80 µA mm⁻¹ cm⁻², which is comparable to RGO working electrodes made by electrochemical reduction.