From the Discovery of the Giant Magnetocaloric Effect to the Development of High‐Power‐Density Systems
Source abstract
Abstract
Abstract Caloric cooling and heating promise an efficient and reliable alternative to ubiquitous vapor‐compression technology. In 1976, the very first near‐room‐temperature caloric system is developed, but it took another 20 years for this technology to fully bloom and gain global attention. The discovery of the giant magnetocaloric effect in Gd5Si2Ge2 and the advance of the first long‐operating magnetic refrigerator, both in 1997, due to the Ames National Laboratory and Astronautics Corporation of America cooperation, are two milestones that sparked ongoing interest in caloric research, which continues to thrive to this day. This review presents a brief history of caloric heat pumping, from the discovery of the magnetocaloric effect to the most recent developments in materials and systems. The contributions of Ames National Laboratory of the U.S. Department of Energy are highlighted, celebrating its 30‐year anniversary in caloric research and paying tribute to two outstanding scientists, Vitalij K. Pecharsky and Karl A. Gschneidner, Jr., who inspired the caloric community for decades. The paper concludes with insights into remaining research and development challenges that must be addressed to enable the market transition of caloric technology and its widespread adoption.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Magnetic and transport properties of perovskites and related materials · Shape Memory Alloy Transformations · Inorganic Chemistry and Materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Ames National Laboratory U.S. Department of Energy Iowa State University Ames IA 50011 USA
Department of Materials Science and Engineering Iowa State University Ames IA 50011 USA
Funding
National Aeronautics and Space Administration
References (100+)
Show source-provided references
1. “The International Renewable Energy Agency (IRENA). Power to heat and cooling: Status” https://www.irena.org/Innovation‐landscape‐for‐smart‐electrification/Power‐to‐heat‐and‐cooling/Status(accessed: February 2025).
2. “Global Cooling Prize” https://globalcoolingprize.org(accessed: January 2025).
3. 10.1016/S0140-7007(97)00089-310.1016/S0140-7007(97)00089-3 ↗
4. 10.1016/j.energy.2012.05.04010.1016/j.energy.2012.05.040 ↗
5. 10.1023/A:100549690022010.1023/A:1005496900220 ↗
6. “U.S. Environmental Protection Agency (EPA). Inventory of U.S. Greenhouse Gas Emissions and Sinks 1990 to 2020 EPA 430‐R‐22‐003 2022. EPA report” https://www.epa.gov/system/files/documents/2022‐04/us‐ghg‐inventory‐2022‐main‐text.pdf(accessed: February 2024).
7. 10.1038/d41586-023-02444-510.1038/d41586-023-02444-5 ↗
8. 10.1557/s43581-024-00121-210.1557/s43581-024-00121-2 ↗
9. 10.1016/j.ijrefrig.2020.09.01910.1016/j.ijrefrig.2020.09.019 ↗
10. E.Comission Technology Readiness Level: Guidance Principles for Renewable Energy Technologies – Final Report2017 https://op.europa.eu/en/publication‐detail/‐/publication/d5d8e9c8‐e6d3‐11e7‐9749‐01aa75ed71a1/language‐en (accessed: March 2025).
11. 10.1063/1.11152010.1063/1.111520 ↗
12. 10.1051/jphystap:01917007001030010.1051/jphystap:019170070010300 ↗
13. 10.1140/epjh/e2013-40001-910.1140/epjh/e2013-40001-9 ↗
14. Weiss P. · Comptes Rendus · 1918 · 166 · 352
15. 10.1002/andp.1926386251710.1002/andp.19263862517 ↗
16. 10.1021/ja01407a00310.1021/ja01407a003 ↗
17. 10.1103/PhysRev.43.76810.1103/PhysRev.43.768 ↗
18. 10.1063/1.32317610.1063/1.323176 ↗
19. 10.1063/1.32500910.1063/1.325009 ↗
20. J. A.Barclay W. A.Steyert (US Patent Office) US4332135 1982.
21. 10.1038/nenergy.2016.13410.1038/nenergy.2016.134 ↗
22. 10.1126/science.adi547710.1126/science.adi5477 ↗
23. 10.1002/aenm.20190374110.1002/aenm.201903741 ↗
24. Kirol L. D. · 1988
25. Green G. · 1990
26. 10.1038/nmat475110.1038/nmat4751 ↗
27. Mudryk Y. · IEEE Magn. Soc. Newsletter · 2023 · 63 · 13
28. V. K.Pecharsky Jr.Gschneidner A.Karl (US Patent Office) US5537826 1996.
29. 10.1007/978-1-4615-2522-6_17910.1007/978-1-4615-2522-6_179 ↗
30. 10.1063/1.155821010.1063/1.1558210 ↗
31. 10.1103/PhysRevB.58.R1472110.1103/PhysRevB.58.R14721 ↗
32. 10.1002/1521-4095(200105)13:9<683::AID-ADMA683>3.0.CO;2-O10.1002/1521-4095(200105)13:9<683::AID-ADMA683>3.0.CO;2-O ↗
33. K. A.Gschneidner Jr. A. O.Pecharsky V. K.Pecharsky (US Patent Office) US6589366 2003.
34. 10.1016/0375-9601(90)90819-A10.1016/0375-9601(90)90819-A ↗
35. 10.1038/nmat139510.1038/nmat1395 ↗
36. 10.1038/nmat333410.1038/nmat3334 ↗
37. 10.1088/1009-1963/9/7/01610.1088/1009-1963/9/7/016 ↗
38. 10.1038/415150a10.1038/415150a ↗
39. “Prototype wine cooler using magnetic refrigeration International Institute of Refrigeration” https://iifiir.org/en/news/prototype‐wine‐cooler‐using‐magnetic‐refrigeration(accessed: December 2024).
40. 10.1007/978-1-4757-9047-4_22210.1007/978-1-4757-9047-4_222 ↗
41. 10.1016/j.ijrefrig.2006.07.01410.1016/j.ijrefrig.2006.07.014 ↗
42. S.Russek J.Auringer A.Boeder J.Chell J.Leonard S.Jacobs C.Zimm presented atFourth IIF‐IIR International Conf. on Magnetic Refrigeration at Room Temperature The International Institute of Refrigeration (IIR) Baotou China 2010.
43. Jacobs S. · J. Japan Soc. Appl. Electromagn. Mech. · 2013 · 21 · 21
44. 10.1016/j.ijrefrig.2013.09.02510.1016/j.ijrefrig.2013.09.025 ↗
45. 10.1016/j.ijrefrig.2006.07.01910.1016/j.ijrefrig.2006.07.019 ↗
46. 10.1007/978-3-319-08741-210.1007/978-3-319-08741-2 ↗
47. 10.1038/nmat159310.1038/nmat1593 ↗
48. 10.1103/PhysRevB.101.22440210.1103/PhysRevB.101.224402 ↗
49. 10.1103/PhysRevB.72.02441610.1103/PhysRevB.72.024416 ↗
50. 10.1016/j.scriptamat.2011.12.04210.1016/j.scriptamat.2011.12.042 ↗
51. 10.1098/rsta.2015.030510.1098/rsta.2015.0305 ↗
52. 10.1088/1361-6463/aa9bd010.1088/1361-6463/aa9bd0 ↗
53. 10.1063/5.023868910.1063/5.0238689 ↗
54. 10.1103/PhysRevB.97.01420210.1103/PhysRevB.97.014202 ↗
55. 10.1016/j.actamat.2019.09.02310.1016/j.actamat.2019.09.023 ↗
56. 10.1016/j.actamat.2019.05.00410.1016/j.actamat.2019.05.004 ↗
57. 10.3390/cryst1009081510.3390/cryst10090815 ↗
58. 10.1016/j.jmps.2013.08.00410.1016/j.jmps.2013.08.004 ↗
59. 10.1126/science.126116410.1126/science.1261164 ↗
60. 10.1007/s40830-024-00475-z10.1007/s40830-024-00475-z ↗
61. R.Choudhary J.Cui D. D.Johnson (Unpublished Tests) Machine‐Learned Shape‐Memory Alloys with Zero Hysteresis Using Geometric Non‐Linear Theory: The Case of Ni‐Ti‐Cu2023.
62. 10.1002/adma.20231285610.1002/adma.202312856 ↗
63. 10.1016/j.actamat.2024.11995210.1016/j.actamat.2024.119952 ↗
64. 10.1038/s41524-023-01095-410.1038/s41524-023-01095-4 ↗
65. 10.1016/j.actamat.2023.11878410.1016/j.actamat.2023.118784 ↗
66. 10.1016/j.actamat.2021.11747210.1016/j.actamat.2021.117472 ↗
67. 10.1038/s41524-018-0072-010.1038/s41524-018-0072-0 ↗
68. 10.1016/j.actamat.2021.11747710.1016/j.actamat.2021.117477 ↗
69. 10.1016/j.jmmm.2018.03.02010.1016/j.jmmm.2018.03.020 ↗
70. 10.1063/1.36711310.1063/1.367113 ↗
71. 10.1063/1.491387810.1063/1.4913878 ↗
72. 10.1002/aenm.20150036110.1002/aenm.201500361 ↗
73. 10.1016/j.actamat.2021.11716210.1016/j.actamat.2021.117162 ↗
74. 10.1063/1.500417310.1063/1.5004173 ↗
75. 10.1016/j.enconman.2019.11194810.1016/j.enconman.2019.111948 ↗
76. 10.1016/j.ijrefrig.2010.08.01410.1016/j.ijrefrig.2010.08.014 ↗
77. 10.1088/2515-7655/acc1a010.1088/2515-7655/acc1a0 ↗
78. 10.1016/j.ijrefrig.2021.01.01810.1016/j.ijrefrig.2021.01.018 ↗
79. 10.1039/D2EE00099G10.1039/D2EE00099G ↗
80. 10.1016/j.rser.2023.11320410.1016/j.rser.2023.113204 ↗
81. 10.1016/j.cryogenics.2022.10358810.1016/j.cryogenics.2022.103588 ↗
82. J.Barclay “Magnetocaloric Hydrogen Liquefaction” https://www.hydrogen.energy.gov/docs/hydrogenprogramlibraries/pdfs/review21/in004_barclay_2021_o‐pdf.pdf?sfvrsn=7991fe24_0 In DOE Hydrogen Program. 2021 Annual Merit Review and Peer Evaluation Meeting (accessed: March 2025).
83. 10.1016/j.cryogenics.2019.01.00910.1016/j.cryogenics.2019.01.009 ↗
84. 10.1038/s41467-018-05268-410.1038/s41467-018-05268-4 ↗
85. 10.1103/PhysRevMaterials.6.11440610.1103/PhysRevMaterials.6.114406 ↗
86. 10.1016/j.jallcom.2024.17418610.1016/j.jallcom.2024.174186 ↗
87. 10.1016/j.jallcom.2023.17229710.1016/j.jallcom.2023.172297 ↗
88. 10.1039/D4TC02247E10.1039/D4TC02247E ↗
89. J. J.Hugenroth (US Patent Office) US6367281B1 2002.
90. 10.1016/j.ijrefrig.2015.12.00110.1016/j.ijrefrig.2015.12.001 ↗
91. 10.1098/rsta.2015.030910.1098/rsta.2015.0309 ↗
92. 10.1088/2515-7655/acd7a210.1088/2515-7655/acd7a2 ↗
93. G.Mohn “Team SMAlloygator Wins CASMART Student Design Challenge” https://news.engineering.iastate.edu/2021/06/11/team‐smalloygator‐wins‐casmart‐student‐design‐challenge/(accessed: June 2021).
94. 10.1038/s41467-017-01275-z10.1038/s41467-017-01275-z ↗
95. 10.1021/acs.nanolett.1c0175010.1021/acs.nanolett.1c01750 ↗
96. 10.1063/1.508727910.1063/1.5087279 ↗
97. 10.1038/s41535-023-00596-110.1038/s41535-023-00596-1 ↗
98. J.Cui “Elastocaloric Refrigeration for Spaceflight Applications (ERSA)” https://www.nasa.gov/directorates/stmd/space‐tech‐research‐grants/esi/elastocaloric‐refrigeration‐for‐spaceflight‐applications‐esra/(accessed: March 2025).
99. “Magnotherm: The Future of Cooling” https://magnotherm.co(accessed: November 2024).
100. 10.1016/j.apenergy.2024.12469610.1016/j.apenergy.2024.124696 ↗