Collectively Exhaustive MXene and Graphene Oxide Multilayer for Suppressing Shuttling Effect in Flexible Lithium Sulfur Battery

Abstract The shuttling effect of lithium polysulfide (LiPS), which leads to the gravest capacity degradation, is one of the critical problems to hindering the commercialization of lithium–sulfur batteries (LSBs). Here, collectively exhaustive Ti₃C₂T_x MXene and graphene oxide (GO) multilayers are reported to suppress the shuttling effect by utilizing both physical inhibition of micro/mesoporous and chemical absorption of surface functional groups. The abundant surface functional groups of GO and MXene attract the positively charged lithium ion (Li⁺) and eject the negatively charged polysulfides (S_n^2–) through electrostatic affinity and repulsion. A simple approach using vacuum filtration is utilized to encapsulate elemental sulfur (S₈) between GO and MXene film (GSM), acting as a permselective separator and functionalized current collector, respectively. The functionally antagonistic GSM directly plays a role in a cathode for LSBs and exhibits a specific capacity of 1425 mAh g^–1 at 0.1C in the initial cycle. The abundant functional groups, which can chemisorb the LiPSs, result in a high cyclic retention of ≈85.1% after 500 cycles. Furthermore, a flexible LSB is demonstrated with a PEO‐LiTFSI electrolyte based on the flexibility of the exceptionally thin GSM due to the 2D nanomaterials, MXene and graphene oxide.