journal article·2022-11Open access

Charge Distribution Controls On‐Target Separation of Low Nucleophilicity Anions in Layered Double Hydroxides (Adv. Mater. Interfaces 31/2022)

Tomohito Sudare, Shuhei Tamura, Maru Kashiwazaki, Yuki Nakamura, Kenta Kawaguchi, Hiromasa Shiiba, Kazunori Fujisawa, Mongkol Tipplook, Hideki Tanaka, Fumitaka Hayashi, Katsuya Teshima

Advanced Materials Interfaces· Volume 9· Issue 31

Abstract

Nitrate Ion-Separation The underlying prerequisite for materials design to achieve on-target separation of low nucleophilic nitrate ions has been unclear. By fabricating cation-ordered layered double hydroxides (LDHs) via topochemical reaction, in article number 2201484, Tomohito Sudare, Katsuya Teshima, and colleagues demonstrate that the hexagonal arrangement effectively facilitates a stable guest–guest interactions–hydrogen-bond between the interlayer nitrate ions and water molecules, which contributes to efficient nitrate ion-separation.
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Research context

OpenAlex topics: Covalent Organic Framework Applications · Chemical Synthesis and Characterization · Layered Double Hydroxides Synthesis and Applications

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Affiliations

Research Initiative for Supra‐Materials (RISM) Shinshu University 4‐17‐1 Wakasato Nagano 380–8553 Japan

Department of Materials Chemistry Faculty of Engineering Shinshu University 4‐17‐1 Wakasato Nagano 380–8553 Japan

References

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