A Facile Way for Acquisition of a Nanoporous Pt–C Catalyst for Oxygen Reduction Reaction

Abstract Here, the concept of preferential leaching of cerium oxide on ternary Pt–C–CeO₂ compound is demonstrated in order to develop a cost‐effective catalyst for the cathode in proton exchange membrane fuel cells. The Pt–C–CeO₂ thin film catalyst is prepared by simultaneous magnetron co‐sputtering of Pt, C, and CeO₂. The morphology, structure, and composition of the Pt–C–CeO₂ layer are characterized by transmission electron microscopy, scanning electron microscopy, energy dispersive X‐ray spectroscopy, X‐ray photoelectron spectroscopy, and X‐ray diffraction. Both half‐cell and single‐cell tests are performed to determine its activity and durability. During an activation electrochemical cycling procedure, CeO₂ is leached from the compound, leaving behind a porous Pt–C matrix which exhibits almost 3 times higher electrochemically active surface area in comparison with pure Pt with identical loading before and even after accelerated degradation tests in the half‐cell. When used as the cathode in a single‐cell membrane electrode assembly, decomposed Pt–C–CeO₂ also shows greater power density than pure Pt.