journal article·2017-08Open access

Giant Enhancement of Polarization and Strong Improvement of Retention in Epitaxial Ba0.6Sr0.4TiO3‐Based Nanocomposites

OonJew Lee, Ahmed Kursumovic, Zhenxing Bi, Chen‐Fong Tsai, Haiyan Wang, Judith L. MacManus‐Driscoll

Advanced Materials Interfaces· Volume 4· Issue 15

Abstract

In Ba0.6Sr0.4TiO3 (BSTO)‐based epitaxial nanocomposite films increased P r values are demonstrated by up to a factor of 3 compared to standard BSTO films. A strongly reduced temperature coefficient of polarization retention is also obtained, i.e., 0.07% °C−1 compared to 0.24% °C−1. Piezopoling with only marginal leakage current is also achieved up to 200 °C, the highest temperature studied. The origin of the improved performance is the incorporation of Sm2O3 nanopillars in the films which acted as stiff vertical nanoscaffolds, inducing a strong tetragonal distortion in the BSTO (up to 1.033(7) in terms of the out‐of‐plane/in‐plane lattice dimensions). The films have comparable performance to industry‐standard Pb(Zr,Ti)O3 films, at the same time as being Pb‐free.
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Research context

OpenAlex topics: Ferroelectric and Piezoelectric Materials · Acoustic Wave Resonator Technologies · Dielectric materials and actuators

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Materials Science and Metallurgy University of Cambridge 27 Charles Baggage Street Cambridge CB3 0FS UK

School of Fundamental Science Universiti Malaysia Terengganu Kuala Terengganu 21030 Malaysia

Department of Electrical and Computer Engineering Texas A&M University College Station TX 77843 USA

Materials Science and Engineering Program Texas A&M University College Station TX 77843 USA

School of Materials Engineering Purdue University West Lafayette IN 47907 USA

Funding

European Research Council · National Science Foundation · Engineering and Physical Sciences Research Council

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