Room Temperature Hydrogen Physisorption on Exposed Metals in A Highly Cross‐Linked Organo‐Iron Complex

A highly cross-linked polymeric complex (MTF-Fe) with exposed under-coordinated iron metals is synthesized through the reaction of Fe-modified-melamine with terephthaldehyde for room temperature hydrogen storage via physisorption. The MTF-Fe shows a hydrogen storage capacity of 1.7 wt% at 298K and 100 atm. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.