Synthesis of unsymmetrical biaryls via low‐coordination palladium species
Source abstract
Abstract
The biaryl unit is a fundamental feature of a large number of nonlinear optical materials and liquid crystals. Unsymmetrical biaryls (see figure) have been shown to be of particular interest, exhibiting amongst other things a high electro‐optic coefficient. The synthesis of the new unsymmetrical biaryls involves the palladium‐complexcatalyzed coupling of an organometallic derivative with an aromatic halide. magnified image
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Research context
OpenAlex topics: Catalytic Cross-Coupling Reactions · Axial and Atropisomeric Chirality Synthesis · Catalytic C–H Functionalization Methods
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