Tailoring the molecular sieving action of zeolite Y with MOCVD‐type reagents

Geoffrey A. Ozin; Mark R. Steele

doi:10.1002/adma.19940060410

journal article·1994-04

Tailoring the molecular sieving action of zeolite Y with MOCVD‐type reagents

Geoffrey A. Ozin, Mark R. Steele

Advanced Materials· Volume 6· Issue 4

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Source abstract

Abstract

A novel method of engineering the supercage aperture in zeolite Y that can produce zeolites with highly tunable pore sizes is described. The room temperature reaction of metal organic chemical vapor deposition species such as (CH₃)₂Zn or (CH₃)₂Cd with Brønsted acid sites in H_πNa_36−nY leads to anchored ZOZnCH₃ or ZOCdCH₃ moieties located at specific sites in the supercage of zeolite Y that can discriminate between H₂S and H₂Se. This degree of chemoselectivity will increase the number of potential practical applications of molecular sieves.

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Research context

Materials processing

OpenAlex topics: Zeolite Catalysis and Synthesis · Metal-Organic Frameworks: Synthesis and Applications · Catalytic Processes in Materials Science

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (11)

Show source-provided references

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