journal article·2022-01Open access

A Sodium–Antimony–Telluride Intermetallic Allows Sodium‐Metal Cycling at 100% Depth of Discharge and as an Anode‐Free Metal Battery (Adv. Mater. 1/2022)

Yixian Wang, Hui Dong, Naman Katyal, Hongchang Hao, Pengcheng Liu, Hugo Celio, Graeme Henkelman, John Watt, David Mitlin

Advanced Materials· Volume 34· Issue 1

Abstract

Anode-Free Batteries In article number 2106005, Hui Dong, David Mitlin, and co-workers report an intermetallic for anode-free batteries. The winter scene shows a birthday cake with lit candles that are melting: the cake represents the complex structure of a cycled sodium-metal anode with the protruding candles being the dendrites. A slice, obtained by cryogenic focused ion beam (FIB) microscopy, further reveals the underlying porosity that develops during repeated plating and stripping of the metal. The thick non-uniform red frosting on the cake represents the unstable solid electrolyte interphase (SEI) that drives the dendrite growth.
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Research context

OpenAlex topics: Advanced Battery Materials and Technologies · Fuel Cells and Related Materials · Electrocatalysts for Energy Conversion

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Affiliations

Materials Science and Engineering Program & Texas Materials Institute (TMI) The University of Texas at Austin Austin TX 78712‐1591 USA

Department of Chemistry The University of Texas at Austin Austin TX 78712 USA

Center for Integrated Nanotechnologies Los Alamos National Laboratory Los Alamos NM 87545 USA

References

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