Novel materials for non‐ablative optical recording
Source abstract
Abstract
Novel materials for optical data storage based on a new recording method are described. Instead of pits or refractive index changes being produced in the recording medium, marks are the result of the generation of near ‐IR absorbing dyes, which leads to a change in the absorption of light from the read laser. The new materials, thin films of tellurium (IV) dihalide bound in a glass together with a sensitizing dye, undergo thermal reductive elimination of halogen on expousure to laser radiation. This technique could ind applications in electrophotographic mastering.
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Research context
OpenAlex topics: Photorefractive and Nonlinear Optics · Semiconductor Lasers and Optical Devices · Phase-change materials and chalcogenides
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References (23)
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23. We have equated viscosity effects with the effects of pressure with regard to ΔS#. Just as pressure can assist reactions with negative volumes of activation (negative values of ΔS#) or retard reactions with positive volumes of activation (positive values of ΔS#) high viscosity can retard reactions with positive volumes of activation. The reductive elimination reactions described here form two molecules from one and intuitively proceed with positive volumes of activation.