Novel tellurium‐containing p‐terphenoquinone analogues: Preparation and unique redox properties of paramagnetic tellurium‐centered radical cation complexes
Source abstract
Abstract
Amphoteric tellurium‐containing π‐donors'acceptors are reported. The electrical and magnetic properties of the charge‐transfer complexes and radical cation salts prepared from 1 (see Figure; X Te, R1 Me) are presented. 1 exhibits a remarkably low oxidation potential compared with S analogues and a one‐step two‐electron reduction potential, indicating that its derivatives could also be of use as the first Te‐containing organic electron acceptors. magnified image
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Research context
OpenAlex topics: Magnetism in coordination complexes · Organic and Molecular Conductors Research · Organoselenium and organotellurium chemistry
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References (20)
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