journal article·2016-07Open access

Ferromagnetism: Sulfur Doping Induces Strong Ferromagnetic Ordering in Graphene: Effect of Concentration and Substitution Mechanism (Adv. Mater. 25/2016)

Jiří Tuček, Piotr Błoński, Zdeněk Sofer, Petr Šimek, Martin Petr, Martin Pumera, Michal Otyepka, Radek Zbořil

Advanced Materials· Volume 28· Issue 25

Abstract

R. Zbořil and co-workers show that doping a graphene lattice with sulfur induces magnetic centers which display ferromagnetic order below ≈62 K. As described on page 5045, sulfur doping promotes magnetically active configurations resembling the gamma-thiothiapyrone motif. Enhanced magnetic properties of sulfur-doped graphene are attributed to two unpaired electrons from each sulfur atom injected into the graphene conducting band where they are delocalized between the S and C atoms.
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Research context

OpenAlex topics: Graphene research and applications · 2D Materials and Applications · Supercapacitor Materials and Fabrication

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Affiliations

Regional Centre of Advanced Technologies and Materials Department of Physical Chemistry Faculty of Science Palacky University Šlechtitelů 27 783 71 Olomouc Czech Republic

Department of Inorganic Chemistry University of Chemistry and Technology Prague Technická 5 166 28 Prague 6 Czech Republic

Division of Chemistry and Biological Chemistry School of Physical and Mathematical Sciences Nanyang Technological University 637371 Singapore

References

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