journal article·2007-01-20

Quantized Double‐Layer Charging of Rhodium2057(Tridecylamine)321 Clusters Using Differential Pulse and Cyclic Voltammetry

B. A. Kakade, S. S. Shintri, B. R. Sathe, S. B. Halligudi, V. K. Pillai

Advanced Materials· Volume 19· Issue 2
Publisher page

Abstract

Rhodium nanoclusters show a series of quantized double-layer-charging events in solution-phase voltammetry at room temperature (see figure). The unusual variation in the FWHM for both the cathodic and anodic regions in differential pulse voltammetry experiments can be explained by several complex factors including reorganization and disproportionation of charged clusters coupled with electron-transfer processes pertaining to the Rh–Rh bonds.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Electrochemical Analysis and Applications · Molecular Junctions and Nanostructures · Electrocatalysts for Energy Conversion

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (27)

Show source-provided references
1. 10.1021/ja972319y10.1021/ja972319y ↗
2. 10.1126/science.280.5372.209810.1126/science.280.5372.2098 ↗
3. 10.1021/ar960266410.1021/ar9602664 ↗
4. 10.1016/j.jelechem.2003.10.03810.1016/j.jelechem.2003.10.038 ↗
5. 10.1021/la048489n10.1021/la048489n ↗
6. 10.1063/1.178176310.1063/1.1781763 ↗
7. 10.1039/b516650k10.1039/b516650k ↗
8. 10.1016/S1388-2481(02)00324-710.1016/S1388-2481(02)00324-7 ↗
9. 10.1021/cm990620310.1021/cm9906203 ↗
10. 10.1021/jp011280n10.1021/jp011280n ↗
11. 10.1126/science.106933610.1126/science.1069336 ↗
12. 10.1021/nl049516x10.1021/nl049516x ↗
13. 10.1021/ja051803v10.1021/ja051803v ↗
14. 10.1021/ja049605b10.1021/ja049605b ↗
15. 10.1021/nl048100g10.1021/nl048100g ↗
16. 10.1021/cm048379210.1021/cm0483792 ↗
17. 10.1021/ja034930510.1021/ja0349305 ↗
18. 10.1021/jp982822c10.1021/jp982822c ↗
19. 10.1021/la001052510.1021/la0010525 ↗
20. 10.1021/ja015820610.1021/ja0158206 ↗
21. 10.1021/cm000653e10.1021/cm000653e ↗
22. 10.1021/jp051455j10.1021/jp051455j ↗
23. 10.1021/ja010682610.1021/ja0106826 ↗
24. 10.1016/S0022-0728(81)80138-610.1016/S0022-0728(81)80138-6 ↗
25. Frolov V. M. · Kinet. Catal. · 1994 · 35 · 800
26. NIST Vibrational Spectroscopy Databasehttp://webbook.nist.gov/chemistry/vib‐ser.html(accessed December 2006).
27. 10.1021/ic50187a04610.1021/ic50187a046 ↗