Crystal designing organic ferrimagnets**
Source abstract
Abstract
Controlling the structure of a molecular assembly by using a molecule carrying both a functional site and an orientation controlling site has recently been achieved. The latter site plays the role of arranging the functional molecules by utilizing hydrogen bonding interactions or charge‐transfer interactions between the orientation controlling sites. The functional molecules then self‐assemble to create highly ordered molecular architectures. The technique is explained.
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Research context
OpenAlex topics: Porphyrin and Phthalocyanine Chemistry · Supramolecular Chemistry and Complexes · Magnetism in coordination complexes
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (22)
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21. Crystal data: C26H31N7O10 Mw= 601.57 triclinic space group P1 a=11.514(1) b=17.112(2) c=7.481(1) Å α=90.86(1) β=99.59(1) γ=89.58(1)° V =1453.1(3) Å3 Z = 2 D =1.374 gcm–3. R = 0.080 for 3657 independent reflections [|Fo|≥3δ(|Fo|)] and 512 parameters.
22. Crystal data: C33H43N8O10 C6H6 Mw= 789.87 triclinic space group P1 a 11.526(3) h = 13.260(2) c = 7.288(2) Å α = 106.57(2) β = 106.34(3) γ = 90.38(2)° V 1020.0(5) Å3 Z = 1 Dc= 1.286 gcm–3. R = 0.059 for 2807 independent reflections [|Fo|≥3δ(|Fo|)] and 710 parameters.