journal article·2000-08

A New Organic Conductor and a Novel Structural Phase Transition in the BEDT-TTF Trihalide Family

E. Laukhina, J. Vidal-Gancedo, S. Khasanov, V. Tkacheva, L. Zorina, R. Shibaeva, J. Singleton, R. Wojciechowski, J. Ulanski, V. Laukhin, J. Veciana, C. Rovira

Advanced Materials· Volume 12· Issue 16
Publisher page

Abstract

A new quasi-2D molecular conductorbased on BEDT-TTF with an assembly of the trihalide anions I2Br–, IBr2–, and BrICl– is presented here. This set of anions promotes the formation of α′- and α‴-type conducting layers (see Figure, top) along with a low-temperature α‴→β″ transition seen for the first time in BEDT-TTF salts.
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Research context

OpenAlex topics: Organic and Molecular Conductors Research · N-Heterocyclic Carbenes in Organic and Inorganic Chemistry · Molecular Junctions and Nanostructures

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