Supramolecular Structure of Extrinsically Chiral Porphyrin Hetero‐Assemblies and Achiral Analogues
Source abstract
Abstract
Supramolecular structures of porphyrin hetero-assemblies and the achiral analogous are determined through energy dispersive X-ray diffraction. In presence of phenylalanine, CuT4 cationic and H2TTPS anionic porphyrins yield a suprachiral α-helix persisting even after removing the chiral template. The analogous synthesis performed without the template-imprinting agent provides an amorphous arrangement, hence an achiral structure.
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Research context
OpenAlex topics: Porphyrin and Phthalocyanine Chemistry · Surface Chemistry and Catalysis · Supramolecular Chemistry and Complexes
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