Control of Coercivity in Organic‐Based Solid Solution VxCo1–x[TCNE]2·zCH2Cl2 Room Temperature Magnets
Source abstract
Abstract
Solid solutions of VxCo1–x[TCNE]2 composition have been prepared from the reaction of V(CO)6 and Co2(CO)8 in dichloromethane. All magnetically order above 280 K for x > 0.05 and their coercivity increases with decreasing x, reaching a maximum of 270 Oe for x = 0.3 (see Figure). Hence, the magnetic properties of this magnet can be finely tuned via a synthetic organic chemistry methodology.
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Research context
OpenAlex topics: Magnetism in coordination complexes · Catalysis and Oxidation Reactions · Organic and Molecular Conductors Research
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References (20)
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