The first radical salt of the polyoxometalate cluster [P2W18O62]6⊖ with bis(ethylenedithio)tetrathiafulvalene (ET): ET11[P2W18O62] · 3H2O
Source abstract
Abstract
The study of organic donor‐inorganic cluster hybrids has been extended to polyoxometalates with higher nuclearities and different shapes using the heteropolyanion [P2W18O62]6⊖ combined with bis(ethylenedithio)tetrathiafulvalene. The resulting hybrid material is unique in several respects: the new radical salt has an unprecedented stoichiometry and β‐type packing; it is the first well‐characterized radical salt of a polymetalate to exhibit metallic behavior. Further possibilities for investigation are briefly outlined.
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Research context
OpenAlex topics: Polyoxometalates: Synthesis and Applications · Metal-Organic Frameworks: Synthesis and Applications · Nanocluster Synthesis and Applications
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References (25)
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22. This fact precludes an accurate assignment of the charge distribution in the organic slab (see Table 1) for the central C=C distances. A low temperature structural resolution will be performed to obtain more precise information about the charge localization in the ET molecules.
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