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journal article·2024-04Open access

Tailored Design of a Water‐Based Nanoreactor Technology for Producing Processable Sub‐40 Nm 3D COF Nanoparticles at Atmospheric Conditions

Gemma Llauradó‐Capdevila, Andrea Veciana, Maria Aurora Guarducci, Alvaro Mayoral, Ramon Pons, Lukas Hertle, Hao Ye, Minmin Mao, Semih Sevim, David Rodríguez‐San‐Miguel, Alessandro Sorrenti, Bumjin Jang, Zuobin Wang, Xiang‐Zhong Chen, Bradley J. Nelson, Roc Matheu, Carlos Franco, Salvador Pané, Josep Puigmartí‐Luis

Advanced Materials· Volume 36· Issue 14
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Source abstract

Abstract

Abstract Covalent organic frameworks (COFs) are crystalline materials with intrinsic porosity that offer a wide range of potential applications spanning diverse fields. Yet, the main goal in the COF research area is to achieve the most stable thermodynamic product while simultaneously targeting the desired size and structure crucial for enabling specific functions. While significant progress is made in the synthesis and processing of 2D COFs, the development of processable 3D COF nanocrystals remains challenging. Here, a water‐based nanoreactor technology for producing processable sub‐40 nm 3D COF nanoparticles at ambient conditions is presented. Significantly, this technology not only improves the processability of the synthesized 3D COF, but also unveils exciting possibilities for their utilization in previously unexplored domains, such as nano/microrobotics and biomedicine, which are limited by larger crystallites.
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Research context

Nanomaterials

OpenAlex topics: Covalent Organic Framework Applications · Metal-Organic Frameworks: Synthesis and Applications · Luminescence and Fluorescent Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Departament de Ciència de Materials i Química Física Institut de Química Teòrica i Computacional Universitat de Barcelona Barcelona 08028 Spain

Institute of Robotics and Intelligent Systems ETH Zurich Tannenstrasse 3 Zurich CH 8092 Switzerland

Dipartimento di Chimica e Tecnologie del Farmaco Sapienza Università di Roma Roma 00185 Italy

Instituto de Nanociencia y Materiales de Aragón (INMA) CSIC‐Universidad de Zaragoza Zaragoza 50009 Spain

Institute for Advanced Chemistry of Catalonia (IQAC−CSIC) Barcelona 08034 Spain

Departamento de Química Inorgánica Universidad Autónoma de Madrid Madrid 28049 Spain

Departament de Química Inorgànica i Orgànica (Secció de Química Orgànica) Institut de Química Teòrica i Computacional Universitat de Barcelona Barcelona 08028 Spain

Department of Robotics Hanyang University ERICA Campus Ansan‐si 15588 Republic of Korea

International Research Centre for Nano Handling and Manufacturing of China Changchun University of Science and Technology Changchun 130022 China

Zhongshan Institute of Changchun University of Science and Technology Zhongshan 528437 China

Institute of Optoelectronics State Key Laboratory of Photovoltaic Science and Technology Shanghai Frontiers Science Research Base of Intelligent Optoelectronics and Perception Fudan University Shanghai 200433 P. R. China

Departament de Química Inorgànica i Orgànica Institut de Química Teòrica i Computacional Universitat de Barcelona Barcelona 08028 Spain

Institució Catalana de Recerca i Estudis Avançats (ICREA) Pg. Lluís Companys 23 Barcelona 08010 Spain

Funding

Agencia Estatal de Investigación · National Research Foundation of Korea · Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

References (36)

Show source-provided references
1. 10.1098/rsta.2007.000610.1098/rsta.2007.0006 ↗
2. 10.1038/s42004-018-0098-810.1038/s42004-018-0098-8 ↗
3. 10.1039/D1MA00008J10.1039/D1MA00008J ↗
4. 10.1039/C2CS35072F10.1039/C2CS35072F ↗
5. 10.1126/science.112041110.1126/science.1120411 ↗
6. 10.1002/978352782109910.1002/9783527821099 ↗
7. 10.1039/D0CS01027H10.1039/D0CS01027H ↗
8. 10.1038/s41586-022-04443-410.1038/s41586-022-04443-4 ↗
9. 10.1126/science.120274710.1126/science.1202747 ↗
10. 10.1021/acs.chemmater.0c0024610.1021/acs.chemmater.0c00246 ↗
11. 10.1021/jacs.7b0745710.1021/jacs.7b07457 ↗
12. 10.1021/ja204728y10.1021/ja204728y ↗
13. 10.1021/jacs.8b1033410.1021/jacs.8b10334 ↗
14. 10.1016/j.cej.2022.13744710.1016/j.cej.2022.137447 ↗
15. 10.1039/D0CS00620C10.1039/D0CS00620C ↗
16. 10.1126/science.aat767910.1126/science.aat7679 ↗
17. 10.1039/D3RA02202A10.1039/D3RA02202A ↗
18. 10.1021/jacs.5b0414710.1021/jacs.5b04147 ↗
19. 10.1016/j.apmt.2019.10055010.1016/j.apmt.2019.100550 ↗
20. 10.1007/s00396005038010.1007/s003960050380 ↗
21. 10.1039/D0CC02033H10.1039/D0CC02033H ↗
22. 10.1039/C5CC10221A10.1039/C5CC10221A ↗
23. 10.1107/S002188981300353110.1107/S0021889813003531 ↗
24. 10.1107/S002188988100961810.1107/S0021889881009618 ↗
25. 10.1021/ja809625610.1021/ja8096256 ↗
26. 10.1021/jacs.8b0316910.1021/jacs.8b03169 ↗
27. 10.1021/acs.inorgchem.2c0156710.1021/acs.inorgchem.2c01567 ↗
28. 10.1107/S002188989901521610.1107/S0021889899015216 ↗
29. 10.1016/S0001-8686(97)00312-610.1016/S0001-8686(97)00312-6 ↗
30. 10.1021/jacs.9b1238910.1021/jacs.9b12389 ↗
31. 10.1021/acscentsci.6b0033110.1021/acscentsci.6b00331 ↗
32. 10.1021/acs.chemmater.8b0498610.1021/acs.chemmater.8b04986 ↗
33. 10.1021/acsnano.2c1134610.1021/acsnano.2c11346 ↗
34. 10.1002/adma.20230112610.1002/adma.202301126 ↗
35. 10.1002/adfm.20210742110.1002/adfm.202107421 ↗
36. 10.1039/C6CC10188G10.1039/C6CC10188G ↗