Stereoblock Polypropylene as a Prototype Example of Elasticity via a Flip‐Flop Reorientation of Crystals in a Compliant Matrix
Source abstract
Abstract
Elastomeric polypropylene characterized by chains with an isotactic and atactic stereoblock structure shows elastic behavior in a large range of deformations notwithstanding the high degree of crystallinity, because of the occurrence of flip-flop reversible reorientation of crystals of the γ form that occur during stretching and the successive release of tension, as shown schematically in the figure.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: biodegradable polymer synthesis and properties · Advanced Sensor and Energy Harvesting Materials · Polymer crystallization and properties
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (25)
Show source-provided references
1. 10.1002/masy.20035110810.1002/masy.200351108 ↗
2. 10.1016/S0079-6700(03)00024-810.1016/S0079-6700(03)00024-8 ↗
3. 10.1021/ja036282v10.1021/ja036282v ↗
4. 10.1021/ja045684f10.1021/ja045684f ↗
5. 10.1002/adma.20040196810.1002/adma.200401968 ↗
6. 10.1039/tf963590056210.1039/tf9635900562 ↗
7. 10.1021/ma60073a02610.1021/ma60073a026 ↗
8. 10.1002/pol.1976.18014020610.1002/pol.1976.180140206 ↗
9. 10.1016/j.progpolymsci.2005.11.00210.1016/j.progpolymsci.2005.11.002 ↗
10. 10.1021/cm060398j10.1021/cm060398j ↗
11. 10.1002/pol.1959.120341273810.1002/pol.1959.1203412738 ↗
12. 10.1126/science.267.5195.21710.1126/science.267.5195.217 ↗
13. 10.1021/ma00200a00610.1021/ma00200a006 ↗
14. 10.1021/ja00161a07510.1021/ja00161a075 ↗
15. 10.1021/ma00115a00510.1021/ma00115a005 ↗
16. 10.1002/anie.20060002710.1002/anie.200600027 ↗
17. 10.1021/ma020332j10.1021/ma020332j ↗
18. 10.1021/ma020477q10.1021/ma020477q ↗
19. 10.1021/ma011624810.1021/ma0116248 ↗
20. 10.1081/MB-10010756110.1081/MB-100107561 ↗
21. 10.1016/j.polymer.2005.07.02810.1016/j.polymer.2005.07.028 ↗
22. 10.1038/340455a010.1038/340455a0 ↗
23. 10.1002/polb.1986.09024090910.1002/polb.1986.090240909 ↗
24. 10.1021/ma010959m10.1021/ma010959m ↗
25. A. Hotta E. Cochran J. Roukolainen V. Khanna G. H. Fredrickson E. J. Kramer P. D. Hustad A. E. Cherian G. W. Coates Y.‐W. Shin F. Shimizu presented at DYFP2006 13th International Conference on Deformation. Yield and Fracture of Polymers DYFPRolduc Abbey Kerkrade the Netherlands April2006 p. 117.