Photoinduced Diffusion Through Polymer Networks

Photomediated addition-fragmentation chemistry is applied to demonstrate the precisely controlled diffusion of chemical species through polymer networks. Fluorescent groups connected to polymer networks by allyl sulfide moieties become mobile upon irradiation with UV light due to radical-mediated addition-fragmentation bond exchange. Photoinduced transport through the bulk, into solution, and across film interfaces is demonstrated. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.