journal article·2007-10-19

A Methyl Tricyanoethylenecarboxylate‐Based Room‐Temperature Magnet

K. I. Pokhodnya, B. Lefler, J. S. Miller

Advanced Materials· Volume 19· Issue 20
Publisher page

Abstract

A room-temperature magnet of V[MeTCEC]2·0.6(CH2Cl2) composition (MeTCEC = methyl tricyanoethylenecarboxylate) is formed by the reaction of MeTCEC and V(CO)6 (see figure). Analysis of the magnetization indicates a less disordered structure of V[MeTCEC]2·0.6(CH2Cl2) with respect to similarly synthesized V[TCNE]x·0.34(CH2Cl2), presumably because of the much slower reaction of MeTCEC and V(CO)6.
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Research context

OpenAlex topics: Magnetism in coordination complexes · Porphyrin and Phthalocyanine Chemistry · Organic and Molecular Conductors Research

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