journal article·2007-10-19

Unique Polymorphism of Oligothiophenes

H. Pan, P. Liu, Y. Li, Y. Wu, B. S. Ong, S. Zhu, G. Xu

Advanced Materials· Volume 19· Issue 20
Publisher page

Abstract

Quarterthiophenes with long pendant alkyl side-chains exhibit a unique, hitherto unreported polymorphism arising from side-chain comformational changes. Those with long backbone structures show two different side-chain conformationally induced polymorphs, one with a fully extended side-chain and one with a bent side-chain conformations. This unique polymorphism is a result of subtle differences in molecular architecture and can be induced by crystallization conditions.
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Research context

OpenAlex topics: Organic Electronics and Photovoltaics · Conducting polymers and applications · Synthesis and Properties of Aromatic Compounds

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