journal article·2005-03-22

Electron and Hole Dynamics on Isolated Chains of a Solution‐Processable Poly(thienylenevinylene) Derivative in Dilute Solution

P. Prins, L. P. Candeias, A. J. J. M. van Breemen, J. Sweelssen, P. T. Herwig, H. F. M. Schoo, L. D. A. Siebbeles

Advanced Materials· Volume 17· Issue 6
Publisher page

Abstract

Intrachain dynamics of charge carriers on isolated chains of a derivative of the π-conjugated polymer, poly(thienylenevinylene) (see Figure), in solution are investigated using time-resolved microwave conductivity measurements. High intrachain mobilities, of 0.23 ± 0.04 and 0.38 ± 0.02 cm2 V–1 s–1, are found for electrons and holes, respectively. It is observed that electrons become trapped at defects or impurities, in contrast to holes.
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Research context

OpenAlex topics: Organic Electronics and Photovoltaics · Conducting polymers and applications · Organic Light-Emitting Diodes Research

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